1-碘-2,4-二甲基-6-硝基苯合成路线 （共 4 条）
反应条件
1: With sulfuric acid; sodium nitrite in acetic acid
T=15 - 75°C;
2: With urea; potassium iodide
参考文献
Liang, Yuxue; Gao, Shuang; Wan, Huihui; Wang, Junwei; Chen, Huilin; Zheng, Zhuo; Hu, Xinquan
Tetrahedron Asymmetry, 2003 , vol. 14, # 10 p. 1267 - 1273
反应条件
1.1: 86 percent / 96 percent HNO3; Ac2O / 1.17 h / 7 °C
2.1: NaNO2; conc. H2SO4 / acetic acid / 15 - 75 °C
2.2: 69 percent / aq. KI; urea
View Scheme
参考文献
Liang, Yuxue; Gao, Shuang; Wan, Huihui; Wang, Junwei; Chen, Huilin; Zheng, Zhuo; Hu, Xinquan
Tetrahedron Asymmetry, 2003 , vol. 14, # 10 p. 1267 - 1273
反应条件
1: 84 percent / Cu / dimethylformamide / Heating
2: 87 percent / Na2S2 / ethanol / Heating
View Scheme
参考文献
Everitt,P.M. et al.
Journal of the Chemical Society, 1960 , p. 4587 - 4590
反应条件
copper in N,N-dimethyl-formamide
Ullmann coupling; Heating;
参考文献
Liang, Yuxue; Gao, Shuang; Wan, Huihui; Wang, Junwei; Chen, Huilin; Zheng, Zhuo; Hu, Xinquan
Tetrahedron Asymmetry, 2003 , vol. 14, # 10 p. 1267 - 1273
