Holland, Patrick L.; Andersen, Richard A.; Bergman, Robert G.; Huang, Jinkun; Nolan, Steven P.
Journal of the American Chemical Society, 1997 , vol. 119, # 52 p. 12800 - 12814
Holland, Patrick L.; Andersen, Richard A.; Bergman, Robert G.; Huang, Jinkun; Nolan, Steven P.
Journal of the American Chemical Society, 1997 , vol. 119, # 52 p. 12800 - 12814
Holland, Patrick L.; Andersen, Richard A.; Bergman, Robert G.; Huang, Jinkun; Nolan, Steven P.
Journal of the American Chemical Society, 1997 , vol. 119, # 52 p. 12800 - 12814
Holland, Patrick L.; Andersen, Richard A.; Bergman, Robert G.; Huang, Jinkun; Nolan, Steven P.
Journal of the American Chemical Society, 1997 , vol. 119, # 52 p. 12800 - 12814
Holland, Patrick L.; Andersen, Richard A.; Bergman, Robert G.; Huang, Jinkun; Nolan, Steven P.
Journal of the American Chemical Society, 1997 , vol. 119, # 52 p. 12800 - 12814
Mo2Cl4(PEt3)4 in deuterated toluene T=-5.1°C; ΔH(excit.); ΔS(excit.); different temperatures; KineticsThermodynamic data;
参考文献
Chisholm, Malcolm H.; McInnes, Jacqueline M.
Journal of the Chemical Society - Dalton Transactions, 1997 , # 16 p. 2735 - 2743
→
反应条件
methanol in benzene A solution of Os(CCPh)2(CO)(P-i-Pr3)2(PMe3) and PMe3 is kept for 1 h at room temp. (N2).; The Os-compd. is filtered off, washed with methanol, dried in vac., elem. anal.;
参考文献
Werner, H.; Meyer, U.; Esteruelas, M. A.; Sola, E.; Oro, L. A.
Journal of Organometallic Chemistry, 1989 , vol. 366, p. 187 - 196
→
反应条件
in toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.2:1) in toluene;;
