in [3.3.1]nonane Sn sulfide and freshly pptd. Cu heating in nonane in a sealed tube for 40 h at 160°C, liquid fraction decanting off, solid washing with nonane, solvent removing from combined solns.; Me2SnO isolated as Me2SnCl2;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 245 - 252
in methanol-d4 a mixt. of Me3GeSnMe3 and Me3SnCl in CD3OD was kept for 30 h, reaction was followed by (1)H NMR spectroscopy; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 25 - 38
in tetrachloromethane aliquots of CF3COOH (ca. 0.1 equiv) were added to a soln. of the stannane in CCl4 in a NMR tube containing cyclohexane as a reference, reactionwas monitored by (1)H NMR spectroscopy; reactions were rapid and complete before the spectrum was obtained; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 7 - 24
