methyllithium in not given byproducts: n-butyllithium; Sn-compd. was reacted with MeLi in THF or DME at -60°C for 10 min; equil. react.; analysed by (1)H and (13)C NMR spectra;
参考文献
Journal of the American Chemical Society, , vol. 106, # 11 p. 3376 - 3377
methyllithium in not given byproducts: CH3OCH2OCH(CH3)Li; Sn-compd. was reacted with MeLi in THF or DME at -60°C for 10 min; equil. react.; analysed by (1)H and (13)C NMR spectra;
参考文献
Journal of the American Chemical Society, , vol. 106, # 11 p. 3376 - 3377
methyllithium in not given byproducts: CH3OCH2OC6H10Li; Sn-compd. was reacted with MeLi in THF or DME at -60°C for 10 min; equil. react.; analysed by (1)H and (13)C NMR spectra;
参考文献
Journal of the American Chemical Society, , vol. 106, # 11 p. 3376 - 3377
in water soln. of Sn compound (0.1 M in HCl and NaCl, buffered at pH 4.5) placedin vial, sealed with "crimp on" teflon-lined silicon-rubber septum, andleft in a darkroom for 60 days;; monitoring by gas chromatography;;
in neat (no solvent, gas phase) Irradiation (UV/VIS); Sn2Me6 at pressure 0.3 mTorr in 100 Torr of N2 photolyzed at 193 nm; 25-100 photolysis laser shots of photolysis pulce energy 40-50 mJ/pulse;
参考文献
Becerra, Rosa; Boganov, Sergey E.; Egorov, Mikhail P.; Faustov, Valery I.; Krylova, Irina V.; Nefedov, Oleg M.; Walsh, Robin
Journal of the American Chemical Society, 2002 , vol. 124, # 25 p. 7555 - 7562
methyllithium in not given equimolar amts. of MeLi and stannylsulfurdiimide reacting under Ar, Me4Sn removing by fractional distn.; identified by elem. anal., IR and NMR spectra;
参考文献
Journal of Organometallic Chemistry, , vol. 236, # 1 p. 53 - 60
