in [3.3.1]nonane a mixt. of Sn sulfide and freshly pptd. Cu heating in nonane in a sealed evacuated tube for 40 h at 160°C, liquid product decanting off,solid washing with nonane, solvent removing from combined solns. at 30°C/1 torr; purified by distillation in vacuo;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 245 - 252
educts separately condensed into a reactor held at -196°C, then allowed to react for 15 min at room temp., at 10-fold excess of (CH3)2Cd; volatile products were removed and analyzed, identification by NMR;
参考文献
Krause, L. J.; Morrison, J. A.
Inorganic Chemistry, 1980 , vol. 19, p. 604 - 607
in methanol Kinetics; a mixt. of 0.197 M Me3GeSnMe3 and 0.194 M Me2SnCl2 in methanol was keptfor 160 min, reaction was followed by (1)H NMR spectroscopy; second order kinetics, rate const. is given; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 25 - 38
in methanol a mixt. of Me3GeSnMe3 and Me2SnCl2 in methanol was kept for 7 h, reaction was followed by (1)H NMR spectroscopy; most of the reactants have been consumed, Me3GeSnMe2Cl and Me2SnHCl were not found, "dimethyltin polymer" was also present; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 25 - 38
