in dichloromethane byproducts: CH4; excess SnMe4 (ca. 30 equiv.) added to soln. of Pd complex in CH2Cl2; react. mixt. stirred at room temp. for 15 h; soln. evapd.; redissolved in CH2Cl2, filtered over Celite; solvent evapd.; recrystd. from CH2Cl2 at -20°C; elem. anal.;
参考文献
Angewandte Chemie - International Edition, , vol. 49, # 11 p. 1986 - 1989
in chloroform-d1 soln. of SnMe4, MeSnPh3, benzoyl chloride and benzylchlorobis(triphenylphosphine)palladium(II) in CDCl3 heated at 65°C in NMR tube; not isolated, detected by NMR;
参考文献
Journal of the American Chemical Society, , vol. 105, p. 6129
in dichloromethane dropwise addn. of Me4Sn to a soln. of the B-compound under Ar at room temp.;; evapn. of solvent and Me3SnCl, fractionated distn., elem. anal.;;
in benzene Kinetics; byproducts: CH3WCl4; react. of WCl6 with Me4Sn (ratio 1:2) in C6H6 (double-jacketted react. vessel, Ar, H2O as inert gas); not isolated, detd. by IR, UV, GC;
参考文献
Journal of Molecular Catalysis, , vol. 65, p. 253 - 260
