in diethyl ether Sn2Me6 (1.12 mmol) in Et2O treated with MeLi (1.20 mmol, 1.00 M soln. in Et2O) under Ar, stirred for 30 min at 0°C, TMTH (1.12 mmol) added via syringe, stirred for 30 min at room temp., cooled to 0°C, quenched with water; H2 collected with gas measuring device, GC analysis of org. layer;
参考文献
Reimann, Werner; Kuivila, Henry G.; Farah, Dan; Apoussidis, Theodorus
Organometallics, 1987 , vol. 6, p. 557 - 565
in tetrahydrofuran under argon, compounds were added at -78°C, stirring at this temp. for 5 min, mixt. was warmed to 25°C for 10 min and cooled to -78°C, mixt was transfered to a soln. of water in THF; solvent was removed under vacuum, resulting oil was purified by glpc, elem. anal., mass spectrum;
