hydrogenchloride in methanol Kinetics; 8.5 M aq. HCl was added to a methanol soln. of the stannane in a NMR tube, reaction was followed by (1)H NMR spectroscopy for 48 h; rate consts. according to different reaction paths are given; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 7 - 24
hydrogenchloride in methanol Kinetics; byproducts: Me3SiCl, Me3SiOSiMe3; 8.5 M aq. hydrochloric acid was added to a methanol soln. of the stannane in a NMR tube, reaction was followed by (1)H NMR spectroscopy for 1 d; 54percent of the substrate has been consumed, rate consts. according to different reaction paths are given; not isolated, identified by (1)H NMR spectrum;
参考文献
Cuthberston, Matthew J.; Hawker, Darryl W.; Wells, Peter R.
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 7 - 24
hydrogenchloride in methanol a mixt. of Me6Sn2 and Me3SnCl in MeOH was allowed to react for 70 h until a yellow colour characteristic of the "dimethyl polymer" appeared, one drop of 8.5 M aq. HCl was added, mixt. was kept for 10 min, reaction was followed by (1)H NMR spectroscopy; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 7 - 24
