hydrogen; palladium 10 on activated carbon in tetrahydrofuran; ethanol T=20°C; P=2327.23 Torr; 1 - 2 h; Product distribution / selectivity;

hydrogen; palladium 10 on activated carbon in tetrahydrofuran; ethanol T=20°C; 24 h;

暂无反应条件数据

in methanol; Pd-C

1: SOCl2 / 1 h / 60 °C 2: CH2Cl2 / 1 h / 40 °C 3: 1.) NaNH2 / 1.) toluene, RT, 10 min, 2.) toluene, RT, 40 min 4: H2O, ethan. KOH / ethanol / 24 h / Heating View Scheme

1: CH2Cl2 / 1 h / 40 °C 2: 1.) NaNH2 / 1.) toluene, RT, 10 min, 2.) toluene, RT, 40 min 3: H2O, ethan. KOH / ethanol / 24 h / Heating View Scheme

hydroxylamine hydrochloride in ethanol; water 24 h; Heating;

1: 93 percent / n-BuLi / hexane; diethyl ether / 1.) -20 deg C, 50 min, 2.) - 20 deg C, 1 h, 3.) 2 h 2: 74 percent / n-BuLi / hexane; tetrahydrofuran / 1.) -20 deg C --> 0 deg C, 45 min, 2.) 12 h 3: HgCl2 / methanol; H2O / 4 h / Heating 4: KOH / methanol / 2 h / Heating 5: 83 percent / n-BuLi, i-Pr2NH / hexane; tetrahydrofuran / 1.) -25 deg C, 70 min, 2.) 2 h 6: H2NOH*HCl / ethanol; H2O / 24 h / Heating View Scheme

1: 83 percent / n-BuLi, i-Pr2NH / hexane; tetrahydrofuran / 1.) -25 deg C, 70 min, 2.) 2 h 2: H2NOH*HCl / ethanol; H2O / 24 h / Heating View Scheme

1: 74 percent / n-BuLi / hexane; tetrahydrofuran / 1.) -20 deg C --> 0 deg C, 45 min, 2.) 12 h 2: HgCl2 / methanol; H2O / 4 h / Heating 3: KOH / methanol / 2 h / Heating 4: 83 percent / n-BuLi, i-Pr2NH / hexane; tetrahydrofuran / 1.) -25 deg C, 70 min, 2.) 2 h 5: H2NOH*HCl / ethanol; H2O / 24 h / Heating View Scheme