(4Z)-4-壬烯基-1-醇合成路线 （共 44 条）
反应条件
1: mesyl-Cl, LiBr / acetone View Scheme
参考文献
Hatanaka, Akihiko; Ishii, Yasushige; Tomida, Ichiro
Bioscience, Biotechnology, and Biochemistry, 1995 , vol. 59, # 11 p. 2036 - 2038
反应条件
1: 85 percent / triphenylphosphine, Br2 / CCl4 / 16 h / Ambient temperature 2: 1.) cuprous iodide, 2,2' bipyridyl / 1.) THF, 2 deg C, 10 min, 2.) THF, a) 2 deg C, 2 h, b) RT, 15 h 3: p-toluenesulfonic acid / methanol; H2O / 15 h / 20 °C View Scheme
参考文献
Tolstikov, G. A.; Odinokov, V. N.; Galeeva, R. I.; Bakeeva, R. S.; Akhunova, V. R.
Chemistry of Natural Compounds, 1982 , vol. 18, # 2 p. 219 - 224
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 2 p. 239 - 245
反应条件
1: 95 percent / 6.5 h / -5 - 0 °C View Scheme
参考文献
Tolstikov, G. A.; Odinokov, V. N.; Galeeva, R. I.; Bakeeva, R. S.; Akhunova, V. R.
Chemistry of Natural Compounds, 1982 , vol. 18, # 2 p. 219 - 224
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 2 p. 239 - 245
反应条件
1: 95 percent / 6.5 h / -5 - 0 °C View Scheme
参考文献
Tolstikov; Odinokov; Galeeva; et al.
Tetrahedron Letters, 1979 , vol. No.50, p. 4851 - 4854
反应条件
1: tetrahydrofuran / 0.33 h / 20 °C 2: LiBr / tetrahydrofuran; hexamethylphosphoric acid triamide / 2 h / Heating 3: 81 percent / dimethylformamide / 4 h / 110 °C 4: 98 percent / LDA / tetrahydrofuran; hexamethylphosphoric acid triamide / -78 - -50 °C 5: 92 percent / p-TsOH / methanol / 16 h / 20 °C 6: 88 percent / Na(Hg); Na2HPO4 / methanol / 21 h / 20 °C 7: 91 percent / LiAlH4 / tetrahydrofuran / Heating View Scheme
参考文献
Organic Letters, , vol. 1, # 6 p. 845 - 848
反应条件
1: 85 percent / triphenylphosphine, Br2 / CCl4 / 16 h / Ambient temperature 2: 1.) cuprous iodide, 2,2' bipyridyl / 1.) THF, 2 deg C, 10 min, 2.) THF, a) 2 deg C, 2 h, b) RT, 15 h 3: p-toluenesulfonic acid / methanol; H2O / 15 h / 20 °C 4: 91 percent / pyridine / 24 h / Ambient temperature View Scheme
参考文献
Tolstikov, G. A.; Odinokov, V. N.; Galeeva, R. I.; Bakeeva, R. S.; Akhunova, V. R.
Chemistry of Natural Compounds, 1982 , vol. 18, # 2 p. 219 - 224
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 2 p. 239 - 245
反应条件
diisobutylaluminium hydride in diethyl ether; toluene
T=-10°C; 1.5 h;
参考文献
Odinokov, V. N.; Galeeva, R. I.; Ishmuratov, G. Yu.; Kargapol'tseva, T. A.; Sokol'skaya, O. V.; et al.
Journal of Organic Chemistry USSR (English Translation), 1990 , vol. 26, # 11 p. 1986 - 1989
Zhurnal Organicheskoi Khimii, 1990 , vol. 26, # 11 p. 2299 - 2303
反应条件
NiCl2((PPh3)P)2 in diethyl ether; toluene
T=20°C; 96 h;
参考文献
Ducoux, Jean-Philippe; Le Menez, Patrick; Kunesch, Nicole; Kunesch, Gerhard; Wenkert, Ernest
Tetrahedron, 1992 , vol. 48, # 31 p. 6403 - 6412
反应条件
1: (CH3COO)2Hg / Heating
2: triisobutylaluminium / 1,2-dichloro-ethane / 0.25 h / 25 °C
View Scheme
参考文献
Takai; Mori; Oshima; Nozaki
Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 2 p. 446 - 451
反应条件
NiCl2((PPh3)P)2 in diethyl ether; toluene
96 h; Ambient temperature;
参考文献
Ducoux, Jean-Philippe; Menez, Patrick Le; Kunesch, Nicole; Kunesch, Gerhard; Wenkert, Ernest
Tetrahedron Letters, 1990 , vol. 31, # 18 p. 2595 - 2598
