(4Z)-4-壬烯基-1-醇合成路线 （共 44 条）
反应条件
lithium aluminium tetrahydride in diethyl ether
参考文献
Bestmann; Koschatzky; Schaetzke; et al.
1981 , vol. No. 9, p. 1705 - 1720
反应条件
1: methylaluminum bis(2,6-diphenylphenoxide) (reagent B) / toluene / -20 °C
2: NaBH4 / methanol / 0.08 h / Ambient temperature
View Scheme
参考文献
Nonshita, Katsumasa; Banno, Hiroshi; Maruoka, Keiji; Yamamoto, Hishashi
Journal of the American Chemical Society, 1990 , vol. 112, # 1 p. 316 - 322
反应条件
sodium tetrahydroborate in methanol
0.0833333 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Nonshita, Katsumasa; Banno, Hiroshi; Maruoka, Keiji; Yamamoto, Hishashi
Journal of the American Chemical Society, 1990 , vol. 112, # 1 p. 316 - 322
反应条件
tri-isobutyl aluminium in 1,2-dichloro-ethane
T=25°C; 0.25 h; Yield given. Yields of byproduct given;
参考文献
Takai; Mori; Oshima; Nozaki
Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 2 p. 446 - 451
反应条件
iso-propylmagnesium bromide; NiCl2(PnBu3)2 in tetrahydrofuran
48 h; Heating; Yields of byproduct given;
参考文献
Ducoux, Jean-Philippe; Menez, Patrick Le; Kunesch, Nicole; Wenkert, Ernest
Journal of Organic Chemistry, 1993 , vol. 58, # 5 p. 1290 - 1292
反应条件
potassium hydroxide in methanol; water
24 h; Ambient temperature;
参考文献
Tolstikov, G. A.; Odinokov, V. N.; Galeeva, R. I.; Bakeeva, R. S.; Akhunova, V. R.
Chemistry of Natural Compounds, 1982 , vol. 18, # 2 p. 219 - 224
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 2 p. 239 - 245
反应条件
1: 95 percent / PBr3, pyridine / diethyl ether / 1) overnight, r.t., then 2 h, reflux.
2: 1) Na / 1) benzene, DMF, 2) benzene, 16 h, reflux.
3: 60 percent / NaCl / dimethylsulfoxide; H2O / 8 h / 180 °C
4: 95 percent / H2 / Lindlar's catalyst / hexane
5: 70 percent / LiAlH4 / diethyl ether / 1) overnight, r.t., then 6 h, reflux.
View Scheme
参考文献
Vig, O. P.; Sharma, M. L.; Kumari, Sarla; Vohra, Neelam
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 962 - 964
反应条件
1: 1) Na / 1) benzene, DMF, 2) benzene, 16 h, reflux.
2: 60 percent / NaCl / dimethylsulfoxide; H2O / 8 h / 180 °C
3: 95 percent / H2 / Lindlar's catalyst / hexane
4: 70 percent / LiAlH4 / diethyl ether / 1) overnight, r.t., then 6 h, reflux.
View Scheme
参考文献
Vig, O. P.; Sharma, M. L.; Kumari, Sarla; Vohra, Neelam
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 962 - 964
反应条件
1: 60 percent / NaCl / dimethylsulfoxide; H2O / 8 h / 180 °C
2: 95 percent / H2 / Lindlar's catalyst / hexane
3: 70 percent / LiAlH4 / diethyl ether / 1) overnight, r.t., then 6 h, reflux.
View Scheme
参考文献
Vig, O. P.; Sharma, M. L.; Kumari, Sarla; Vohra, Neelam
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 962 - 964
反应条件
1: 95 percent / H2 / Lindlar's catalyst / hexane
2: 70 percent / LiAlH4 / diethyl ether / 1) overnight, r.t., then 6 h, reflux.
View Scheme
参考文献
Vig, O. P.; Sharma, M. L.; Kumari, Sarla; Vohra, Neelam
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 962 - 964
