4-甲氧基-2-硝基苯基硫氰酸酯合成路线 （共 5 条）
反应条件
pyridine in acetic acid
参考文献
Passerini,R.; Purrello,G.
Gazzetta Chimica Italiana, 1960 , vol. 90, p. 1277 - 1289
反应条件
1.1: lithium aluminium tetrahydride / benzene; diethyl ether / Cooling; Reflux; Inert atmosphere 1.2: pH 6 2.1: boric acid / 6 h / Reflux View Scheme
参考文献
THE UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL; JIN, Jian; ROTH, Bryan; FRYE, Stephen
Patent: WO2012/3418 A2, 2012 ;
WO 2012/003418 A2
反应条件
1.1: lithium aluminium tetrahydride / benzene; diethyl ether / Cooling; Reflux; Inert atmosphere 1.2: pH 6 2.1: boric acid / 6 h / Reflux 3.1: hydrogen iodide / 5 h / Reflux View Scheme
参考文献
THE UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL; JIN, Jian; ROTH, Bryan; FRYE, Stephen
Patent: WO2012/3418 A2, 2012 ;
WO 2012/003418 A2
反应条件
1: 2-nitro-4-methoxy-aniline With sulfuric acid; sodium nitrite in water
T=0 - 5°C;
2: potassium thioacyanate With cobalt(II) chloride in water
T=0 - 50°C;
参考文献
THE UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL; JIN, Jian; ROTH, Bryan; FRYE, Stephen
Patent: WO2012/3418 A2, 2012 ;
Location in patent: Page/Page column 56 ;
WO 2012/003418 A2
反应条件
sulfuric acid; copper(I) isothiocyanate
参考文献
Ochiai; Katada
Yakugaku Zasshi, 1940 , vol. 60, p. 543,550; dtsch. Ref. S. 211, 214, 216
Chem.Abstr., 1941 , p. 1786
