B-(9,10-二苯基-2-蒽)硼酸合成路线 (共 6 条)
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 1 h;
2: With boric acid trimethyl ester in tetrahydrofuran; hexane
T=-78 - 20°C; 3 h;
3: With hydrogenchloride in tetrahydrofuran; hexane; water
1 h;
参考文献
IDEMITSU KOSAN CO., LTD.
Patent: EP1734038 A1, 2006 ;
Location in patent: Page/Page column 43; 46 ;
反应条件
1: 2-bromo-9,10-diphenylanthracene With n-butyllithium in tetrahydrofuran
T=-78°C; 1 h;
2: boric acid trimethyl ester in tetrahydrofuran
T=20°C; 4 h;
3: With hydrogenchloride in tetrahydrofuran; water
参考文献
Samsung Mobile Display Co., Ltd.
Patent: EP2292604 A2, 2011 ;
Location in patent: Page/Page column 22 ;
反应条件
1: 2-bromo-9,10-diphenylanthracene With n-butyllithium in tetrahydrofuran; hexane
T=-80°C;
2: boron triethoxide in tetrahydrofuran; hexane
2 h;
3: With hydrogenchloride; water in tetrahydrofuran; hexane
12 h;
参考文献
TDK Corporation
Patent: US2011/295017 A1, 2011 ;
Location in patent: Page/Page column 21 ;
反应条件
1: 2-bromo-9,10-diphenylanthracene With n-butyllithium in tetrahydrofuran; hexane
T=-78 - 0°C; 1 h;
2: boric acid trimethyl ester in tetrahydrofuran; hexane
T=-78 - 20°C; 3 h;
3: With hydrogenchloride; water in tetrahydrofuran; hexane
1 h;
参考文献
IDEMITSU KOSAN CO., LTD.
Patent: WO2006/67931 A1, 2006 ;
Location in patent: Page/Page column 54 ;
反应条件
1.1: toluene; diethyl ether; anhydrous butyl ether / 6 h / -20 °C
2.1: potassium iodide; acetic acid; NaH2PO2 / 6 h / Reflux
3.1: n-butyllithium / hexane; tetrahydrofuran / -80 °C
3.2: 2 h
3.3: 12 h
View Scheme
参考文献
TDK Corporation
Patent: US2011/295017 A1, 2011 ;
反应条件
1.1: potassium iodide; acetic acid; NaH2PO2 / 6 h / Reflux
2.1: n-butyllithium / hexane; tetrahydrofuran / -80 °C
2.2: 2 h
2.3: 12 h
View Scheme
参考文献
TDK Corporation
Patent: US2011/295017 A1, 2011 ;