10-(2-萘基)蒽-9-硼酸合成路线 （共 9 条）
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane T=-78°C; Inert atmosphere; 2: With tri-isopropoxy-borane in tetrahydrofuran; hexane T=-78 - 20°C; 3: With hydrogenchloride; water in tetrahydrofuran; hexane
参考文献
PARK, KYUNG-HO; Delaney, William J.
Patent: US2010/237769 A1, 2010 ;
Location in patent: Page/Page column 7-8 ;
反应条件
1: 9-bromo-10-(naphthalene-2-yl)anthracene With tert.-butyl lithium in tetrahydrofuran T=-78°C; 2: boric acid trimethyl ester in tetrahydrofuran T=0 - 20°C; 3 h; 3: With hydrogenchloride; water in tetrahydrofuran T=20°C; 1.5 h;
参考文献
LG Chem, Ltd.
Patent: EP2311826 A2, 2011 ;
Location in patent: Page/Page column 65 ;
反应条件
1: 9-bromo-10-(naphthalene-2-yl)anthracene With n-butyllithium in tetrahydrofuran; hexane T=-60°C; 0.666667 h; Inert atmosphere; 2: tri-isopropoxy-borane in tetrahydrofuran; hexane T=-60 - 20°C; 3 h; Inert atmosphere; 3: With water in tetrahydrofuran; hexane Inert atmosphere;
参考文献
US2012/267615 A1, ;
Page/Page column 51 ;
参考文献
Idemitsu Kosan Co., Ltd.
Patent: US2007/152565 A1, 2007 ;
反应条件
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / ethanol; water; toluene 2: n-butyllithium / tetrahydrofuran View Scheme
参考文献
Journal of Materials Chemistry, , vol. 21, # 34 p. 12969 - 12976
反应条件
1.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / ethylene glycol dimethyl ether; water / 3 h / 80 °C 2.1: n-butyllithium / hexane; tetrahydrofuran / 0.67 h / -60 °C / Inert atmosphere 2.2: 3 h / -60 - 20 °C / Inert atmosphere 2.3: Inert atmosphere View Scheme
反应条件
1.1: bromine; acetic acid / chloroform / 0 - 20 °C 2.1: tert.-butyl lithium / tetrahydrofuran / -78 °C 2.2: 3 h / 0 - 20 °C 2.3: 1.5 h / 20 °C View Scheme
反应条件
1: magnesium / tetrahydrofuran 2: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / ethanol; water; toluene 3: n-butyllithium / tetrahydrofuran View Scheme
参考文献
Journal of Materials Chemistry, , vol. 21, # 34 p. 12969 - 12976
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethylene glycol dimethyl ether; water
8 h; Heating / reflux;
参考文献
IDEMITSU KOSAN CO., LTD.
Patent: EP1602648 A1, 2005 ;
Location in patent: Page/Page column 35 ;
