(R)-(-)-2-辛醇合成路线 (共 140 条)
反应条件
lipase CC in hexane lipase P; Product distribution;
参考文献
Tetrahedron, , vol. 46, # 12 p. 4231 - 4240
反应条件
NaCO3 in water; acetonitrile T=25°C; Rate constant;
参考文献
Tetrahedron Letters, , vol. 24, # 49 p. 5541 - 5542
反应条件
Sulfolobus shibatae DSM 5389 in phosphate buffer T=20°C; pH=2 - 3; 120 h; Product distribution; Further Variations:Reagents;
参考文献
Organic and Biomolecular Chemistry, , vol. 3, # 14 p. 2652 - 2656
反应条件
potassium hydroxide Heating;
参考文献
Reyes; Juaristi
Synthetic Communications, 1995 , vol. 25, # 7 p. 1053 - 1058
反应条件
3 A molecular sieve; Humicola insolens ferulic acid esterase T=45°C; 216 h;
参考文献
Bioorganic Chemistry, , vol. 33, # 4 p. 325 - 337
反应条件
cytochrome P450 BM-3_A74G F87V L188Q T=37°C; pH=7.5; 22 h; aq. bufferEnzymatic reaction; optical yield given as percent eestereoselective reaction;
参考文献
Wu, Li-Lan; Yang, Chung-Ling; Lo, Feng-Chun; Chiang, Chih-Hsiang; Chang, Chun-Wei; Ng, Kok Yaoh; Chou, Ho-Hsuan; Hung, Huei-Ying; Chan, Sunney I.; Yu, Steve S.-F.
Chemistry - A European Journal, 2011 , vol. 17, # 17 p. 4774 - 4787
反应条件
1,4-dioxane; titanium(IV) isopropylate; bis{(4R,5R)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato-O,O'}titanium(IV); zinc(II) chloride 1a.) Et2O, r.t., 2 h, 1b.) 45 min, 2a.) -78 deg C, 1 h, 2b) -30 deg C; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron, , vol. 48, # 27 p. 5719 - 5730
反应条件
in acetone 20 h; Ambient temperaturelipase PS, phosphate buffer; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 5 p. 557 - 562
反应条件
copper(l) iodide; magnesium 1.) THF, 1 h, 2.) THF, O deg C, 1 h; Yield given. Multistep reaction. Title compound not separated from byproducts;
参考文献
Synthetic Communications, , vol. 23, # 15 p. 2159 - 2169
反应条件
sodium; aluminum dichloride hydride 1.) ether, 0 deg C, 2 h; 2.) liquid ammonia; Yield given. Multistep reaction;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 5 p. 334 - 335