3-甲基-1,2-丁二烯合成路线 （共 178 条）
反应条件
in diethyl ether
1.) -78 deg C, 2.) -30 deg C,; Yield given. Yields of byproduct given;
参考文献
Halazy, Serge; Hevesi, Laszlo
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5242 - 5246
反应条件
1: diethyl ether / 1.) -78 deg C, 2.) -30 deg C,
2: 59 percent / silver perchlorate, Na2CO3 / nitromethane / 6 h / -15 °C
View Scheme
参考文献
Halazy, Serge; Hevesi, Laszlo
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5242 - 5246
反应条件
1: diethyl ether / 1.) -78 deg C, 2.) -30 deg C,
2: silver perchlorate, CaCO3 / nitromethane / 6 h / -15 °C
View Scheme
参考文献
Halazy, Serge; Hevesi, Laszlo
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5242 - 5246
反应条件
1: diethyl ether / 1.) -78 deg C, 2.) -30 deg C,
2: silver perchlorate, CaCO3 / nitromethane / 6 h / -15 °C
View Scheme
参考文献
Halazy, Serge; Hevesi, Laszlo
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5242 - 5246
反应条件
1: diethyl ether / 1.) -78 deg C, 2.) -30 deg C,
2: 1.) silver perchlorate, CaCO3, 2.) tri-n-butyltin hydride, AIBN / 1.) nitromethane, -15 deg C, 2.) benzene, reflux, 4.5 h
View Scheme
参考文献
Halazy, Serge; Hevesi, Laszlo
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5242 - 5246
反应条件
1: diethyl ether / 1.) -78 deg C, 2.) -30 deg C,
2: 1.) silver perchlorate, CaCO3, 2.) tri-n-butyltin hydride, AIBN / 1.) nitromethane, -15 deg C, 2.) benzene, reflux, 4.5 h
View Scheme
参考文献
Halazy, Serge; Hevesi, Laszlo
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5242 - 5246
反应条件
T=160°C; 288 h; Further byproducts given;
参考文献
Pasto, Daniel J.; Yang, Shun-Hua
Journal of the American Chemical Society, 1984 , vol. 106, p. 152 - 157
反应条件
(Pr4N)[PtCl3(ethylene)] in chloroform
T=60°C; 24 h; Yield given;
参考文献
Renzi, Augusto De; Panunzi, Achille; Saporito, Antonio; Vitagliano, Aldo
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 993 - 996
反应条件
(Pr4N)[PtCl3(ethylene)] in chloroform
T=60°C; 24 h; Yield given;
参考文献
Renzi, Augusto De; Panunzi, Achille; Saporito, Antonio; Vitagliano, Aldo
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 993 - 996
反应条件
(Pr4N)[PtCl3(ethylene)] in chloroform
T=60°C; 24 h; Yield given;
参考文献
Renzi, Augusto De; Panunzi, Achille; Saporito, Antonio; Vitagliano, Aldo
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 993 - 996
