3-甲基-1,2-丁二烯合成路线 （共 178 条）
反应条件
1: <N(CH2CH2CH3)4><PtCl3(C2H4)> / CHCl3 / 24 h / 60 °C
2: 20 percent / <N(CH2CH2CH3)4><PtCl3(C2H4)> / CHCl3 / 24 h / 60 °C
View Scheme
参考文献
Renzi, Augusto De; Panunzi, Achille; Saporito, Antonio; Vitagliano, Aldo
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 993 - 996
反应条件
C21H38AuClNP*C24BF20(1-)*K(1+) in benzene-d6
T=70°C; Markovnikov hydroamination; 9 h; Inert atmosphere;
参考文献
Xiaoming, Zeng; Soleilhavoup, Michele; Bertrand, Guy
Organic Letters, 2009 , vol. 11, # 15 p. 3166 - 3169
参考文献
Ikeda, Hiroshi; Tanaka, Futoshi; Akiyama, Kimio; Tero-Kubota, Shozo; Miyashi, Tsutomu
Journal of the American Chemical Society, 2004 , vol. 126, # 2 p. 414 - 415
反应条件
n-butyllithium in tetrahydrofuran; hexane
to stirred soln. of allene in THF added soln. of BuLi in hexane at -60 °C under N2, stirred at -60 °C for 1 h, added CuBr (1 equiv) at -60 °C, stirred for 30 min at -20 °C; not isolated;
参考文献
Ruitenberg, K.; Meijer, J.; Bullee, R. J.; Vermeer, P.
Journal of Organometallic Chemistry, 1981 , vol. 217, # 2 p. 267 - 271
反应条件
Au(P(OC6H5)3)Cl; trimethylsilylazide; silver trifluoromethanesulfonate; trifluoroacetic acid in dichloromethane; water
T=0 - 20°C; Schlenk techniqueInert atmosphere;
参考文献
Hurtado-Rodrigo, Cesar; Hoehne, Stefanie; Munoz, Maria Paz
Chemical Communications, 2014 , vol. 50, # 12 p. 1494 - 1496
反应条件
1: 1.)n-butyllithium / 1.)THF, pentane
2: Bu3SnH / benzene / Heating; without solvent
View Scheme
参考文献
Apparu, Marcel; Crandall, Jack K.
Journal of Organic Chemistry, 1984 , vol. 49, # 12 p. 2125 - 2130
反应条件
tetrakis(triphenylphosphine) palladium(0) in xylene
A soln. of reagents in xylene was heated for 15 h at 85°C in thepresence of (PPh3)4Pd;; evapd., Kugelrohr distillation;;
参考文献
Killing, H.; Mitchell, T. N.
Organometallics, 1984 , vol. 3, p. 1917 - 1919
反应条件
Ni(trans,trans,trans-1,5,9-cyclododecatriene); N,N,N',N,-tetramethylethylenediamine
1.) THF, from -78 deg C to -15 deg C, 5 h, 2.) THF, 20 deg C, 24 h, 1 bar; Yield given. Multistep reaction;
参考文献
Hoberg, Heinz; Suemmermann, Klaus
Journal of Organometallic Chemistry, 1984 , vol. 275, # 2 p. 239 - 248
反应条件
1: 1.)n-butyllithium / 1.)THF, pentane,-78 deg C, 1 h, 2.)r.t., 4 h
2: Bu3SnH / benzene / Heating; without solvent
View Scheme
参考文献
Apparu, Marcel; Crandall, Jack K.
Journal of Organic Chemistry, 1984 , vol. 49, # 12 p. 2125 - 2130
反应条件
1: KOtBu / pentane
2: nBu3SnH
3: nBu3SnH
View Scheme
参考文献
Maurin,R.; Bertrand,M.
Bulletin de la Societe Chimique de France, 1970 , p. 998 - 1012
