3-甲基-1,2-丁二烯合成路线 （共 178 条）
反应条件
Irradiation; Yield given. Title compound not separated from byproducts;
参考文献
Creary, Xavier
Journal of the American Chemical Society, 1980 , vol. 102, # 5 p. 1611 - 1618
反应条件
C20H37NPPd(1+)*CF3O3S(1-) in benzene-d6
T=70°C; Inert atmosphere; Reagent/catalyst;
参考文献
Zingales, Nicholas C.; Shaffer, Andrew R.; Schmidt, Joseph A. R.
Organometallics, 2013 , vol. 32, # 2 p. 578 - 586
反应条件
methyllithium; diisopropylamine
参考文献
Clinet, Jean-Claude; Linstrumelle, Gerard
Synthesis, 1981 , # 11 p. 875 - 878
反应条件
1: 87 percent / BuLi / tetrahydrofuran; hexane / 5 h / -78 - 20 °C
2: 91 percent / MeOH / TsOH*H2O / 2 h / 20 °C
View Scheme
参考文献
Llerena, Dominique; Buisine, Olivier; Aubert, Corinne; Malacria, Max
Tetrahedron, 1998 , vol. 54, # 32 p. 9373 - 9392
反应条件
n-butyllithium
1.) THF-hexane, -60 degC, then -30 degC, 30 min, 2.) HMPT, -60 degC, then 20 degC, 2.5 h; Yield given. Multistep reaction;
参考文献
Audin, Patrick; Doutheau, Alain; Ruest, Luc; Gore, Jacques
Bulletin de la Societe Chimique de France, 1981 , vol. 2, # 7-8 p. 313 - 318
反应条件
methyllithium; diisopropylamine
参考文献
Creary,X.
Journal of the American Chemical Society, 1977 , vol. 99, # 23 p. 7632 - 7639
反应条件
1: quinoline hydrobromide; quinoline / 130 - 135 °C
2: hydrobromic acid
3: hydrobromic acid
View Scheme
参考文献
Kutscherow
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1913 , vol. 45, p. 1653
Chem. Zentralbl., 1914 , vol. 85, # I p. 754
反应条件
n-butyllithium
1) ether, hexane, RT, 2 h, 2) ether, RT; Yield given. Multistep reaction;
参考文献
Schmidbaur, Hubert; Pollok, Thomas; Reber, Gabriele; Mueller, Gerhard
Chemische Berichte, 1987 , vol. 120, p. 2015 - 2022
反应条件
n-butyllithium
1) THF, -60 deg C, 1 h; Yield given. Multistep reaction;
参考文献
Schmidbaur, Hubert; Pollok, Thomas; Reber, Gabriele; Mueller, Gerhard
Chemische Berichte, 1987 , vol. 120, p. 2015 - 2022
反应条件
hydrogenchloride
T=80 - 90°C; im Rohr;
参考文献
Kondakow
Chemisches Zentralblatt, vol. 24, p. 513
Chemische BerichteChem. Zentralbl., 26Ref. <1893>,96 1890 , vol. 61, # I p. 311
