2,4,6-三甲基苯硼酸合成路线 （共 68 条）
反应条件
1: With sodium hydroxide in methanol T=23°C; 0.25 h; Inert atmosphere; 2: With silver trifluoromethanesulfonate in methanol T=0°C; 0.5 h; Inert atmosphere; 3: With 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate) in acetone T=23°C; 1 h; Inert atmosphereMolecular sieve; regiospecific reaction;
参考文献
Furuya, Takeru; Ritter, Toblas
Organic Letters, 2009 , vol. 11, # 13 p. 2860 - 2863
反应条件
barium dihydroxide; tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane; water Suzuki reaction; 24 h; Heating;
参考文献
Wipf, Peter; Jung, Jae-Kyu
Journal of Organic Chemistry, 2000 , vol. 65, # 20 p. 6319 - 6337
反应条件
2,9-dimethyl-1,10-phenanthroline; palladium diacetate; copper(l) chloride in dimethyl sulfoxide T=50°C; P=760.051 Torr; 12 h;
参考文献
Vellakkaran, Mari; Andappan, Murugaiah M.S.; Kommu, Nagaiah
Green Chemistry, 2014 , vol. 16, # 5 p. 2788 - 2797
反应条件
3,3'-dihexyloxy-1,1'-binaphthylidene-4,4'-dione; potassium hydroxide in tetrahydrofuran; water T=20°C;
参考文献
Cammidge, Andrew N.; Goddard, Victoria H. M.; Schubert, Christopher P. J.; Gopee, Hemant; Hughes, David L.; Gonzalez-Lucas, Daniel
Organic Letters, 2011 , vol. 13, # 22 p. 6034 - 6037
反应条件
potassium phosphate; tris(dibenzylideneacetone)dipalladium (0); tri-cyclo-hexyl-phosphine in toluene T=90°C; Suzuki cross-coupling; 37 h; Title compound not separated from byproducts.;
参考文献
Journal of the American Chemical Society, , vol. 122, # 17 p. 4020 - 4028
反应条件
CpPd(SIPr)Cl; potassium tert-butylate in isopropyl alcohol T=25°C; 24 h; Inert atmosphere;
参考文献
Jin, Zhong; Guo, Su-Xian; Gu, Xiao-Peng; Qiu, Ling-Ling; Song, Hai-Bing; Fang, Jian-Xin
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 10 p. 1575 - 1585
反应条件
caesium carbonate; asymmetric di-N-heterocyclic carbene palladium(II) complex in 1,4-dioxane T=80°C; Suzuki-Miyaura cross-coupling reaction; 24 h;
参考文献
Paulose, Tressia A.P.; Olson, Jeremy A.; Wilson Quail; Foley, Stephen R.
Journal of Organometallic Chemistry, 2008 , vol. 693, # 21-22 p. 3405 - 3410
反应条件
[Ru(tris(2,2'-bipyridyl))3]Cl2·6H2O; anhydrous copper acetate; potassium carbonate in N,N-dimethyl-formamide T=60°C; 12 h; Inert atmosphere26 W fluorescent light bulbs;
参考文献
Ye, Yingda; Sanford, Melanie S.
Journal of the American Chemical Society, 2012 , vol. 134, # 22 p. 9034 - 9037
反应条件
1: water; dichloromethane 2: geraniol; N,N,N',N'-tetramethylguanidine / dichloromethane View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 81, # 12 p. 1621 - 1628
反应条件
potassium phosphate; PCy3∙HBF4; bis(1,5-cyclooctadiene)nickel (0) in tetrahydrofuran T=65°C; Suzuki-Miyaura cross coupling;
参考文献
Chemical Communications, , # 39 p. 4137 - 4139
