2,4,6-三甲基苯硼酸合成路线 （共 68 条）
反应条件
potassium phosphate; R-Phos; bis(dibenzylideneacetone)-palladium(0) in 1,4-dioxane
T=100°C; Suzuki-Miyaura reaction; 2 h; Inert atmosphere;
参考文献
Hoshi, Takashi; Nakazawa, Taichi; Saitoh, Ippei; Mori, Ayako; Suzuki, Toshio; Sakai, Jun-Ichi; Hagiwara, Hisahiro
Organic Letters, 2008 , vol. 10, # 10 p. 2063 - 2066
反应条件
[Pd(1,3-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene)(cinnamyl)Cl]; potassium 2-methyl-2-butoxide in 1,4-dioxane
T=110°C; Buchwald-Hartwig Coupling; 12 h; Inert atmosphereSealed tube;
参考文献
Bastug, Gulluzar; Nolan, Steven P.
Organometallics, 2014 , vol. 33, # 5 p. 1253 - 1258
反应条件
C19H32Cl4P2Pd2; caesium carbonate in 1,4-dioxane
T=90°C; 48 h;
参考文献
Ciric, Ana; Mathey, Francois
Organometallics, 2010 , vol. 29, # 21 p. 4785 - 4786
反应条件
[Pd(1,3-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene)(cinnamyl)Cl]; potassium 2-methyl-2-butoxide in 1,4-dioxane
T=110°C; Buchwald-Hartwig Coupling; 12 h; Inert atmosphereSealed tube;
参考文献
Bastug, Gulluzar; Nolan, Steven P.
Organometallics, 2014 , vol. 33, # 5 p. 1253 - 1258
反应条件
tripotassium phosphate monohydrate; R-Phos; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran
T=50°C; Suzuki coupling; 4 h; Inert atmosphere;
参考文献
Hoshi, Takashi; Saitoh, Ippei; Nakazawa, Taichi; Suzuki, Toshio; Sakai, Jun-Ichi; Hagiwara, Hisahiro
Journal of Organic Chemistry, 2009 , vol. 74, # 10 p. 4013 - 4016
反应条件
dichloro(N-(diphenylphosphino)-N-isopropyl-1,1-diphenylphosphinamine) digold(I); caesium carbonate in acetonitrile
T=65°C; 18 h; chemoselective reaction;
参考文献
Levin, Mark D.; Toste, F. Dean
Angewandte Chemie - International Edition, 2014 , vol. 53, # 24 p. 6211 - 6215
Angew. Chem., 2014 , vol. 126, # 24 p. 6325 - 6329,5
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethylene glycol dimethyl ether
Suzuki cross-coupling reaction; Heating;
参考文献
Goodall, Wendy; Wild, Kerstin; Arm, Kathryn J.; Williams, J.A. Gareth
Journal of the Chemical Society. Perkin Transactions 2, 2002 , # 10 p. 1669 - 1681
反应条件
potassium fluoride; phenylmethyltriethylammonium bromide; tris-(o-tolyl)phosphine; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran
T=60°C; 24 h; Inert atmosphere; Product distribution / selectivity;
参考文献
Zimmermann, Bettina; Dzik, Wojciech I.; Himmler, Thomas; Goossen, Lukas J.
Journal of Organic Chemistry, 2011 , vol. 76, # 19 p. 8107 - 8112
反应条件
palladium diacetate; triphenylphosphine; cesium fluoride in ethylene glycol dimethyl ether
T=70°C; Suzuki coupling; 6 h;
参考文献
Castanet, Anne-Sophie; Colobert, Francoise; Broutin, Pierre-Emmanuel; Obringer, Michel
Tetrahedron Asymmetry, 2002 , vol. 13, # 6 p. 659 - 665
反应条件
[PdCl2(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)(PCy2(2',4',6'-iPr3-2-byphenyl))]; sodium hydroxide in tetrahydrofuran; water; isopropyl alcohol
T=100°C; Suzuki-Miyaura Coupling; 14 h; Schlenk techniqueInert atmosphereGlovebox;
参考文献
Schmid, Thibault E.; Jones, Dale C.; Songis, Olivier; Diebolt, Olivier; Furst, Marc R.L.; Slawin, Alexandra M.Z.; Cazin, Catherine S.J.
Dalton Transactions, 2013 , vol. 42, # 20 p. 7345 - 7353
