2,4,6-三甲基苯硼酸合成路线 (共 68 条)
反应条件
[Rh(OH)(cycloocta-1,5-diene)]2 in methanol
2 h; Inert atmosphereReflux;
参考文献
Matsuda, Takanori; Shiose, Shigeru; Suda, Yuya
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 11-12 p. 1923 - 1926
反应条件
palladium diacetate; sodium carbonate in ethylene glycol dimethyl ether; water
0.333333 h; Ambient temperature;
参考文献
Kang, Suk-Ku; Lee, Hong-Woo; Jang, Su-Bum; Ho, Pil-Su
Journal of Organic Chemistry, 1996 , vol. 61, # 14 p. 4720 - 4724
反应条件
bis[2,4-dimethyl-6-[phenyl(pentafluorphenylimino)methyl]-phenolato]palladium; potassium tert-butylate in isopropyl alcohol
T=60°C; Suzuki-Miyaura cross-coupling; 2 h;
参考文献
Brayton, Daniel F.; Larkin, Timothy M.; Vicic, David A.; Navarro, Oscar
Journal of Organometallic Chemistry, 2009 , vol. 694, # 18 p. 3008 - 3011
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethylene glycol dimethyl ether; water
0.416667 h; Ambient temperature;
参考文献
Kang, Suk-Ku; Lee, Hong-Woo; Jang, Su-Bum; Ho, Pil-Su
Journal of Organic Chemistry, 1996 , vol. 61, # 14 p. 4720 - 4724
反应条件
caesium carbonate; asymmetric di-N-heterocyclic carbene palladium(II) complex in 1,4-dioxane
T=80°C; Suzuki-Miyaura cross-coupling reaction; 24 h;
参考文献
Paulose, Tressia A.P.; Olson, Jeremy A.; Wilson Quail; Foley, Stephen R.
Journal of Organometallic Chemistry, 2008 , vol. 693, # 21-22 p. 3405 - 3410
反应条件
tetrakis(triphenylphosphine) palladium(0); TlOH in N,N-dimethyl acetamide
12 h; Ambient temperature;
参考文献
Anderson, James C.; Namli, Hilmi; Roberts, Craig A.
Tetrahedron, 1997 , vol. 53, # 44 p. 15123 - 15134
反应条件
tetrakis(triphenylphosphine) palladium(0); TlOH in N,N-dimethyl acetamide
12 h; Ambient temperature;
参考文献
Anderson, James C.; Namli, Hilmi; Roberts, Craig A.
Tetrahedron, 1997 , vol. 53, # 44 p. 15123 - 15134
反应条件
1,1'-bis(di-tert-butylphosphino)ferrocene palladium dichloride; triethylamine in water
T=20°C; Suzuki-Miyaura reaction; 2.5 h; Inert atmosphereMicellar solution;
参考文献
Lipshutz, Bruce H.; Petersen, Tue B.; Abela, Alexander R.
Organic Letters, 2008 , vol. 10, # 7 p. 1333 - 1336