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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
d-柠檬烯
合成路线
(共 185 条)
5989-27-5
d-柠檬烯
→
反应条件
99-48-9
香芹醇
+
18383-51-2
(1R,5S)-香芹醇
+
52154-82-2
(+)-反式-对薄荷-2,8-二烯-1-醇
+
22972-51-6
反式-薄荷基-2,8-二烯-1-醇
+
2102-62-7
+
10374-04-6
反应条件
1,4-diaza-bicyclo[2.2.2]octane; air; zinc 5,10,15,20-tetraphenylporphyrin; triphenylphosphine in benzene 3 h; Irradiationmultistep reaction: photosensitized oxygenation of olefines;
参考文献
Tokuyama, Hidetoshi; Nakamura, Eiichi
Journal of Organic Chemistry, 1994 , vol. 59, # 5 p. 1135 - 1138
5989-27-5
d-柠檬烯
→
反应条件
22972-51-6
反式-薄荷基-2,8-二烯-1-醇
+
6909-30-4
(+)-反式-柠檬烯 1,2-环氧化物
+
4680-24-4
柠檬烯-1 2-环氧化物
反应条件
Na6(NH4)4lt;(Mn(II)(H2O)3)2(WO2)2(BiW9O33)2gt;*37H2O; dihydrogen peroxide in dichloromethane 8 h; Ambient temperatureother catalysts; var. reaction times; regioselective epoxidation; Product distribution;
参考文献
Boesing, Michael; Noeh, Andreas; Loose, Ina; Krebs, Bernt
Journal of the American Chemical Society, 1998 , vol. 120, # 29 p. 7252 - 7259
5989-27-5
d-柠檬烯
→
反应条件
203719-54-4
+
185329-56-0
+
96-08-2
反应条件
dihydrogen peroxide in acetonitrile T=80°C; P=760.051 Torr; 24 h; Reagent/catalyst;
参考文献
Balula, Salete S.; Santos, Isabel C.M.S.; Cunha-Silva, Luis; Carvalho, Ana P.; Pires, Joao; Freire, Cristina; Cavaleiro, Jose A.S.; De Castro, Baltazar; Cavaleiro, Ana M.V.
Catalysis Today, 2013 , vol. 203, p. 95 - 102
5989-27-5
d-柠檬烯
→
反应条件
203719-54-4
反应条件
urea hydrogen peroxide addition compound; methyltrioxorhenium (VII) in dichloromethane T=20°C; 0.5 h;
参考文献
Boehlow, Todd R.; Spilling, Christopher D.
Tetrahedron Letters, 1996 , vol. 37, # 16 p. 2717 - 2720
5989-27-5
d-柠檬烯
→
反应条件
203719-54-4
+
96-08-2
反应条件
urea hydrogen peroxide addition compound; methyltrioxorhenium (VII) in dichloromethane T=20°C; 0.25 h; 3 equiv. urea-H2O2 adduct; Yield given. Yields of byproduct given;
参考文献
Brito, Jose A.; Gomez, Montserrat; Muller, Guillermo; Teruel, Helena; Clinet, Jean-Claude; Dunach, Elisabet; Maestro, Miguel A.
European Journal of Inorganic Chemistry, 2004 , # 21 p. 4278 - 4285
5989-27-5
d-柠檬烯
→
反应条件
203719-54-4
+
184488-93-5
反应条件
tert.-butylhydroperoxide; [Mo2(O)4{[2,2'-(1,3-phenylene)bis(4,5-dihydrooxazole-4,2-diyl)]dimethanol}(acac)2] in 1,2-dichloro-ethane 6 h; Reflux; regioselective reaction;
参考文献
Polyhedron, , vol. 72, p. 19 - 26
5989-27-5
d-柠檬烯
→
反应条件
203719-54-4
+
2244-16-8
+
2102-58-1
反应条件
air; benzaldehyde; molecular sieve T=49.85°C; P=22501.8 Torr; 8 h; Yield givenYields of byproduct given. Title compound not separated from byproducts;
参考文献
Raja, Robert; Sankar, Gopinathan; Thomas, John Meurig
Chemical Communications, 1999 , # 9 p. 829 - 830
5989-27-5
d-柠檬烯
→
反应条件
31684-93-2
+
203719-54-4
反应条件
tert.-butylhydroperoxide; C22H38ClMoNO5Si T=55°C; P=760.051 Torr; 24 h; Product distribution; Further Variations:CatalystsSolvents;
参考文献
New Journal of Chemistry, , vol. 25, # 7 p. 959 - 963
5989-27-5
d-柠檬烯
→
反应条件
203719-54-4
+
96-08-2
+
184488-93-5
反应条件
dihydrogen peroxide; Amberlite IRA 900; PW4O24[(C4H9)4N]3 in acetonitrile T=38°C; Epoxidation; 24 h;
参考文献
Mandelli; Voitiski; Schuchardt; Shul'pin
Chemistry of Natural Compounds, 2002 , vol. 38, # 3 p. 243 - 245
5989-27-5
d-柠檬烯
→
反应条件
203719-54-4
+
99-49-0
反应条件
tert.-butylhydroperoxide; tetrabutylammomium bromide; copper dichloride in dichloromethane; water T=25°C; 14 h; Yield given. Yields of byproduct given;
参考文献
Rothenberg, Gadi; Feldberg, Liron; Wiener, Harold; Sasson, Yoel
Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 11 p. 2429 - 2434
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