[(甲基亚胺)二亚甲基]二膦酸合成路线 （共 10 条）
反应条件
ammonia; anhydrous phosphorous acid; methanesulfonic acid in water
T=105 - 145°C; 2.05 - 5 h; Heating / reflux; Product distribution / selectivity;
参考文献
Solutia Europe N.V./S.A.
Patent: EP1681294 A1, 2006 ;
Location in patent: Page/Page column 6-7; 11-13; 14-15 ;
反应条件
in methanol; diethyl ether
T=10°C; Inert atmosphere;
参考文献
Prishchenko, Andrey A.; Livantsov, Mikhail V.; Novikova, Olga P.; Livantsova, Ludmila I.; Petrosyan, Valery S.
Heteroatom Chemistry, 2010 , vol. 21, # 6 p. 430 - 440
反应条件
acetic acid in water
参考文献
Tsirul'nikova, N. V.; Temkina, V. Ya.; Sushitskaya, T. M.; Rykov, S. V.
J. Gen. Chem. USSR (Engl. Transl.), 1981 , vol. 51, # 5 p. 1028 - 1035,859 - 864
反应条件
hydrogenchloride; tetraphosphorus hexa oxide; water; ammonium chloride
T=100 - 110°C; Inert atmosphere; Product distribution / selectivity;
参考文献
Thermphos International B.V.
Patent: EP2112156 A1, 2009 ;
Location in patent: Page/Page column 10 ;
反应条件
hydrogenchloride in water
T=100°C; RefluxInert atmosphere;
参考文献
Prishchenko, Andrey A.; Livantsov, Mikhail V.; Novikova, Olga P.; Livantsova, Ludmila I.; Petrosyan, Valery S.
Heteroatom Chemistry, 2010 , vol. 21, # 6 p. 430 - 440
反应条件
nitric acid in water
Heating;
参考文献
Strunin, B. P.; Khizbullin, F. F.
J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 3.1 p. 537 - 543,477 - 481
反应条件
tetraphosphorus hexa oxide; methanesulfonic acid
T=65 - 95°C; 8 h;
参考文献
STRAITMARK HOLDING AG; NOTTÉ, Patrick; COGELS, Samuel; BURCK, Sebastian
Patent: WO2014/12990 A1, 2014 ;
Location in patent: Page/Page column 26; 29 ;
反应条件
hydrogenchloride; orthophosphorus acid
参考文献
Moedritzer,K.; Irani,R.R.
Journal of Organic Chemistry, 1966 , vol. 31, p. 1603 - 1607
反应条件
in water
T=160°C; 3 h; pH 1.5, 6, 9, 11; 5 M HCl, sealed ampul, other temperatures (100, 150, 175, 200, 250 deg C); Product distribution;
参考文献
Kaslina, N. A.; Polyakova, I. A.; Kessenikh, A. V.; Zhadanov, B. V.; Rudomino, M. V.; et al.
J. Gen. Chem. USSR (Engl. Transl.), 1985 , vol. 55, # 3 p. 534 - 538,472 - 475
反应条件
phosphoric acid
MechanismProduct distribution;
参考文献
Rudomino, M. V.; Kaslina, N. A.; Churilina, N. V.; Poletaeva, I. A.; Kessenikh, A. V.; Kabachnik, M. I.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1984 , vol. 33, # 12 p. 2535 - 2540
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1984 , # 12 p. 2768 - 2773
