1: With (4R,5R)-DIOP; [{RhCl(cod)}2] in tetrahydrofuran T=20°C; 4 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran; water optical yield given as percent ee;
参考文献
Marques, Carolina S.; Burke, Anthony J.
Synthetic Communications, 2008 , vol. 38, # 23 p. 4207 - 4214
1: With CF3O3S(1-)*C45H39N2OPRh(1+); benzo[1,3,2]dioxaborole in tetrahydrofuran T=20°C; 2 h; Inert atmosphere; 2: With dihydrogen peroxide; sodium hydroxide in ethanol; water T=0 - 20°C; optical yield given as percent eeenantioselective reaction;
1: With [CpFe(CO)2(PCy3)][BF4]; phenyl silane T=100°C; 66 h; IrradiationNeat (no solvent)Inert atmosphere; 2: With hydrogenchloride; water in tetrahydrofuran T=20°C; 1 h;
参考文献
Advanced Synthesis and Catalysis, , vol. 354, # 10 p. 1879 - 1884
1: With CpFe(CO)2(PCy3)*I; phenyl silane T=100°C; 24 h; IrradiationNeat (no solvent)Inert atmosphere; 2: With hydrogenchloride; water in tetrahydrofuran T=20°C; 1 h;
参考文献
Advanced Synthesis and Catalysis, , vol. 354, # 10 p. 1879 - 1884
