2,4-二甲基-3-戊醇合成路线 (共 83 条)
反应条件
titanium tetrachloride; lithium in THF-d8 (tetrahydrofuran-d8) T=20°C; McMurry reaction; 24 h; Product distribution; Further Variations:Reagentsmolar ratio;
参考文献
Chemistry - A European Journal, , vol. 7, # 14 p. 3043 - 3051
参考文献
Bulletin des Societes Chimiques Belges, , vol. 35, p. 382
Chem. Zentralbl., , vol. 98, # I p. 715
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 57, p. 1058
Recueil des Travaux Chimiques des Pays-Bas, , vol. 60, p. 61
Justus Liebigs Annalen der Chemie, , vol. 526, p. 65,70
反应条件
tetrahydrofuran in toluene T=0°C; Grignard reaction; addition; reduction; Product distribution; Further Variations:Reagents;
参考文献
Journal of Organometallic Chemistry, , vol. 586, # 2 p. 145 - 149
反应条件
tetrahydrofuran in toluene T=0°C; Grignard reaction; addition; reduction; Product distribution; Further Variations:Reagents;
参考文献
Journal of Organometallic Chemistry, , vol. 586, # 2 p. 145 - 149
反应条件
ethoxymagnesium chloride in diethyl ether T=20°C; Kinetics; Further Variations:Reagents;
参考文献
Journal of Organometallic Chemistry, , vol. 691, # 19 p. 4076 - 4079
反应条件
Cu-Zn-Mg-Al based catalyst; hydrogen reduced T=249.84°C; Product distribution / selectivity;
参考文献
US7314960 B1, ;
Page/Page column 4-8 ;
反应条件
hexafluoroisopropyl alcohol; water T=24.9°C; ΔG, ΔH, ΔS; Thermodynamic dataRate constant;
参考文献
Journal of Organic Chemistry, , vol. 51, # 19 p. 3602 - 3607
反应条件
water in dimethylsulfoxide-d6 Equilibrium constant;
参考文献
Journal of Organic Chemistry, , vol. 61, # 26 p. 9272 - 9279
反应条件
in diethyl ether T=25°C; 1 h; effects of salts (MeOK, t-BuOK, PhOK, (Me2NCH2)2CHOK, MeONa, MeOLi, t-BuOLi, Bu4NBr, BzlEt3NCl), 2,1,1-cryptand and 2,2,2-cryptand; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 55, # 10 p. 3281 - 3286