2,3,4,5,6-五氟苯甲酸合成路线 （共 133 条）
反应条件
sodium hypochlorite; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; potassium bromide in water; acetonitrile T=20°C; aq. buffer;
参考文献
Ignatowska, Jolanta; Shyshkov, Oleg; Zipplies, Tilman; Hintzer, Klaus; Roeschenthaler, Gerd-Volker
Journal of Fluorine Chemistry, 2012 , vol. 141, p. 35 - 40
反应条件
sulfuric acid in water T=145 - 165°C; 15 h;
参考文献
US6392084 B1, ;
Page column 15 ;
反应条件
hydrogenchloride; sodium hypochlorite; chlorine; sodium hydrogencarbonate in water
反应条件
1: pentafluorophenyl chloride With magnesium in tetrahydrofuran T=47 - 65°C; 1.5 h; 2: carbon dioxide in tetrahydrofuran T=-10 - 20°C; 0.416667 h;
参考文献
Albemarle Corporation
Patent: US6365773 B1, 2002 ;
Location in patent: Page column 8-9 ;
反应条件
carbon dioxide in diethyl ether; water react. of (C6F5)3SiH with CH3Li at -50°C, 1 h gives after treatment of the react. product with CO2 in H2O/H(1+) C6F5COOH;
参考文献
Gmelin Handbook: F: PerFHalOrg.SVol.1, 4.2, page 41 - 49
反应条件
dihydrogen peroxide; trifluoroacetic anhydride in dichloromethane 10 h; Heating;
参考文献
Journal of Fluorine Chemistry, , vol. 28, p. 23
反应条件
SbF5; trifluoroacetic acid T=50°C; 11 h;
参考文献
Zonov, Yaroslav V.; Karpov, Victor M.; Platonov, Vyacheslav E.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 9 p. 1058 - 1064
反应条件
1: pentafluorophenyl chloride With magnesium in tetrahydrofuran T=10°C; 2: carbon dioxide in tetrahydrofuran T=-10 - 20°C; P=1137.76 Torr; 0.333333 h;
参考文献
Albemarle Corporation
Patent: US6365773 B1, 2002 ;
Location in patent: Page column 9 ;
反应条件
in tetrahydrofuran 12 hours;;
参考文献
Gmelin Handbook: F: PerFHalOrg.4, 2.2.4, page 68 - 115
反应条件
dihydrogen peroxide in dichloromethane 5 h;
参考文献
Journal of Fluorine Chemistry, , vol. 28, p. 23
