2,3,4,5,6-五氟苯甲酸合成路线 （共 133 条）
反应条件
1: pyridine / benzene 2: H2SO4 View Scheme
参考文献
F: PerFHalOrg.9, 7, page 50 - 101
反应条件
in 1,2,2-trifluoro-trichloroethane T=25°C; different starting concentration ratios; Product distributionRate constantMechanism;
参考文献
Zhao,C.X.; Jiang,X.K.
Journal of Fluorine Chemistry, 1985 , vol. 27, p. 401 - 410
反应条件
in 1,2,2-trifluoro-trichloroethane T=50°C; different starting concentration ratios; Product distributionRate constantMechanism;
参考文献
Zhao,C.X.; Jiang,X.K.
Journal of Fluorine Chemistry, 1985 , vol. 27, p. 401 - 410
反应条件
magnesium anthracene 1.) THF, 0 deg C, 2.) THF, 0 deg C, 40 min; 0 deg C to r.t.; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Chemical Communications, , # 6 p. 693 - 694
反应条件
in various solvent(s) T=20°C; Oxidation; Product distribution;
参考文献
Journal of Physical Organic Chemistry, , vol. 12, # 9 p. 688 - 694
反应条件
SbF5; trifluoroacetic acid T=20°C; 3.5 h;
参考文献
Journal of Fluorine Chemistry, , vol. 128, # 9 p. 1058 - 1064
反应条件
1: pentafluorophenyl chloride; ethylmagnesium bromide in tetrahydrofuran T=25 - 38°C; 1.5 h; 2: carbon dioxide in tetrahydrofuran T=-10 - 20°C; 3 h;
参考文献
Albemarle Corporation
Patent: US6365773 B1, 2002 ;
Location in patent: Page column 8 ;
反应条件
in 1,2,2-trifluoro-trichloroethane T=25°C; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Journal of Fluorine Chemistry, , vol. 27, p. 401 - 410
反应条件
fluorine in sulfuric acid Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of the Chemical Society - Perkin Transactions 1, , # 7 p. 605 - 609
反应条件
in various solvent(s) T=20°C; Oxidation; Product distribution;
参考文献
Journal of Physical Organic Chemistry, , vol. 12, # 9 p. 688 - 694
