(N.N-二乙基)氨基二甲基氯硅烷合成路线 （共 16 条）
反应条件
1: [(2,5-dibromobenzene-1,4-diyl)diethyne-2,1-diyl]-bis(trimethylsilane) With n-butyllithium in diethyl ether; hexane
T=-78°C; 1 h;
2: Et2NMe2SiCl in diethyl ether; hexane
T=-78 - 20°C;
3: ethanol With ammonium chloride in diethyl ether; hexane
T=20°C; 5 h;
参考文献
Mouri, Kazuhiro; Wakamiya, Atsushi; Yamada, Hiroshi; Kajiwara, Takashi; Yamaguchi, Shigehiro
Organic Letters, 2007 , vol. 9, # 1 p. 93 - 96
反应条件
acetyl chloride
1.) THF, 4 h, 2.) THF, 2 h; Yield given. Multistep reaction;
参考文献
Murakami, Masahiro; Suginome, Michinori; Fujimoto, Kenzo; Nakamura, Hiroshi; Andersson, Pher G.; Ito, Yoshihiko
Journal of the American Chemical Society, 1993 , vol. 115, # 15 p. 6487 - 6498
反应条件
in Petroleum ether
Heating;
参考文献
Wannagat,U. et al.
Monatshefte fuer Chemie, 1965 , vol. 96, p. 1902 - 1908
反应条件
in tetrahydrofuran
T=-78 - 20°C; 6 h; Inert atmosphere;
参考文献
Kinoshita, Hidenori; Takahashi, Hirotoshi; Miura, Katsukiyo
Organic Letters, 2013 , vol. 15, # 12 p. 2962 - 2965
反应条件
in tetrahydrofuran
T=-78 - 25°C;
参考文献
Xi, Zhen; Rong, Jianhui; Chattopadhyaya, Jyoti
Tetrahedron, 1994 , vol. 50, # 17 p. 5255 - 5272
反应条件
in diethyl ether
T=20°C; Inert atmosphereReflux;
参考文献
Hoffmann, Florian; Wagler, Joerg; Roewer, Gerhard
European Journal of Inorganic Chemistry, 2010 , # 7 p. 1133 - 1142
