3-{[3-乙酰氨基-5-羟基-6-(羟基甲基)-4-{[3,4,5-三羟基-6-(羟基甲基)四氢-2H-吡喃-2-基]氧基}四氢-2H-吡喃-2-基]氧基}-2-氨基丁酸合成路线 （共 14 条）
反应条件
1: NiCl2*6H2O, H3BO3, NaBH4 / ethanol
2: pyridine
3: 71 percent / PhCH2ONa/PhCH2OH, molecular sieve / CH2Cl2 / 480 h
4: 70 percent / TsOH / acetonitrile
5: 53 percent / Hg(CN)2, HgBr2 / nitromethane; toluene
6: 95 percent / H2 / 9.7percent Pd-C / acetic acid; methanol / 18 h / Ambient temperature
7: 87 percent / NaOMe/MeOH / 0 °C
View Scheme
参考文献
Paulsen; Hoelck
Carbohydrate research, 1982 , vol. 109, p. 89 - 107
反应条件
1: 95 percent / H2 / 9.7percent Pd-C / acetic acid; methanol / 18 h / Ambient temperature
2: 87 percent / NaOMe/MeOH / 0 °C
View Scheme
参考文献
Paulsen; Hoelck
Carbohydrate research, 1982 , vol. 109, p. 89 - 107
反应条件
endo-α-N-acetylgalactosaminidase from Bifidobacterium longum
T=37°C; pH=6; aq. acetate bufferEnzymatic reaction;
参考文献
Ashida, Hisashi; Ozawa, Hayato; Fujita, Kiyotaka; Suzuki, Shun'Ichi; Yamamoto, Kenji
Glycoconjugate Journal, 2010 , vol. 27, # 1 p. 125 - 132
反应条件
Yield given. Multistep reaction;
参考文献
Bencomo, Vicente Verez; Sinay, Pierre
Carbohydrate Research, 1983 , vol. 116, p. C9 - C12
