in dichloromethane Ph3Sb (2 equiv.) added to CH2Cl2 soln. of Bi compd. at room temp.; reacted for 30 min; concd. under reduced pressure; detd. by (1)H NMR spectra;
in methanol; dimethyl sulfoxide treatment of Pd complex in DMSO with Sb(C6H5)3 in methanol at room temp.; refluxing, 5min;; filtration; washing with methanol, ether; recrystn. from benzene; yielding OSb(C6H5)3 by concn. of filtrate, extn. by petroleum ether; elem. anal.;;
参考文献
Datta, Someswar; Agarwala, U. C.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1981 , vol. 20, # 12 p. 1190 - 1195
sodium perchlorate in water; acetonitrile Kinetics; byproducts: HPO4(2-); oxidation at different ionic strength and different temp. (25, 30 and 35°C) and effect of pH; monitored by spectrophotometry;
参考文献
Srinivasan, C.; Pitchumani, K.
Canadian Journal of Chemistry, 1985 , vol. 63, p. 2285 - 2289
Tsvetkov, V. G.; Aleksandrov, Yu. A.; Gulushakova, V. N.; Skorodumova, N. A.; Kol'yakova, G. M.
Journal of General Chemistry USSR (English Translation), 1980 , vol. 50, p. 198 - 201
Zhurnal Obshchei Khimii, 1980 , vol. 50, p. 256 - 258
in dichloromethane all reactions under Ar atm.; soln. of BCl3 in CH2Cl2 added to stirred soln. of triarylstibane at 0°C, stirred for 2 h, allowed to warm toroom temp., solvent removed in vac., oil dissolved in MeOH, stirred for 30 min at room temp., diol added; stirred for 1 h, solvent removed in vac., chromy. (silica-gel, hexane/CH2Cl2);
