by heating in CO2 atmosphere for 4 h at 180-200°C;
参考文献
Liebigs Annalen der Chemie, , vol. 429, p. 123 - 152
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反应条件
in hexane The complex and a slight excess of Pp are refluxed in hexane for 5 min (N2). Some decompn. was observed.; The reaction soln. was filtered and concd. to small vol. under reduced pressure then subjected to preparative thin layer chromy. (silica gel; light petroleum/diethyl ether).;
参考文献
Journal of Organometallic Chemistry, , vol. 342, p. 97 - 110
in toluene a mixt. of cobaltocene and dichlorotriphenylstibine in toluene is heated at 100°C for 3 h, decolorization of soln. and formation of a light-green ppt. is observed,; ppt. is extd. with toluene and toluene is driven off to give triphenylstibine, the residual light-green powder is chlorodicyclopentadienylcobalt;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 61, p. 1236 - 1237
Zhurnal Obshchei Khimii, , vol. 61, p. 1357 - 1359
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反应条件
in toluene a soln. of vanadocene and dichlorotriphenylantimony (2:1) in toluene at room temp. for 20 h, mixt. becomes blue; solvent is removed in vac., triphenylstibine is extd. with hexane, residue consists of dark blue crystals; elem. anal.;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 61, p. 1236 - 1237
Zhurnal Obshchei Khimii, , vol. 61, p. 1357 - 1359
