sodium nitrite in dichloromethane; water mixt. of NaNO2 and the boron contg. salt in a two phase system stirred vigourously at 40°C, 7h (accompanied by evolution of nitrogen oxides); organic layer sepd. from aq. layer, evapn. of CH2Cl2 in vac., residue sepd. by chromy. (silica gel, hexane (9-iodo-m-carbaborane); benzene-hexane 1:1 (9-nitro-m-carbaborane); ether (9-hydroxy-m-carbaborane);
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 57, p. 1199 - 1205
Zhurnal Obshchei Khimii, , vol. 57, p. 1341 - 1347
nitric acid; sodium nitrite in water; trifluoroacetic acid T=24°C; 0.4 h; by application of lH n.m.r. spectroscopy: kinetic studies concerning the nitration of mesitylene; investigation of the influence of additives on the reaction rate; mechanism is proposed; Rate constantMechanismProduct distribution;
参考文献
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , # 10 p. 1659 - 1666
