3,5-二甲氧基苯基三氟甲磺酸酯合成路线 （共 7 条）
反应条件
2,6-dimethylpyridine in dichloromethane T=0°C; 2 h;
参考文献
Ciske, Fred L.; Jones Jr., Winton D.
Synthesis, 1998 , # 8 p. 1195 - 1198
反应条件
sodium carbonate; bis(dibenzylideneacetone)-palladium(0); dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in 1,4-dioxane; water Suzuki-Miyaura cross-coupling; 10 h; Inert atmosphereReflux;
参考文献
Murai, Norio; Yonaga, Masahiro; Tanaka, Keigo
Organic Letters, 2012 , vol. 14, # 5 p. 1278 - 1281
反应条件
pyridine; 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate T=150°C; 0.333333 h; microwave irradiation;
参考文献
Lesma, Giordano; Sacchetti, Alessandro; Silvani, Alessandra
Synthesis, 2006 , # 4 p. 594 - 596
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; 9-borabicyclo[3.3.1]nonane dimer; sodium methylate
1.) THF, rt, 2 h, 2.) THF, reflux, 1 h; Yield given. Multistep reaction;
参考文献
Fuerstner; Seidel
Journal of Organic Chemistry, 1997 , vol. 62, # 8 p. 2332 - 2336
反应条件
potassium methanolate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride
1.) THF, 10 min, 2.) reflux; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Fuerstner, Alois; Seidel, Guenter
Synlett, 1998 , # 2 p. 161 - 162
反应条件
1: 1.) 9-H-9-BBN, 2.) NaOMe, PdCl2(dppf) / 1.) THF, rt, 2 h, 2.) THF, reflux, 1 h
2: 90 percent / 9-iodo-BBN / hexane / Ambient temperature
View Scheme
参考文献
Fuerstner; Seidel
Journal of Organic Chemistry, 1997 , vol. 62, # 8 p. 2332 - 2336
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium methylate; 9-bora-bicyclo[3.3.1]nonane
1.) THF, rt, 2 h, 2.) THF, reflux, 1 h; Yield given. Multistep reaction;
参考文献
Fuerstner; Seidel
Journal of Organic Chemistry, 1997 , vol. 62, # 8 p. 2332 - 2336
