二甲基(3-氯-2-氧代丙基)膦酸酯合成路线 （共 4 条）
反应条件
1: methanephosphonic acid dimethyl ester With n-butyllithium in tetrahydrofuran
T=-78°C; 0.5 h;
2: With copper(l) chloride in tetrahydrofuran
T=-78 - -30°C; 1 h;
3: chloroacetyl chloride in tetrahydrofuran; diethyl ether
T=-30 - 20°C;
参考文献
Yuan, Cheng-Ye; Wang, Ke; Li, Zu-Yi
Heteroatom Chemistry, 2001 , vol. 12, # 6 p. 551 - 556
反应条件
copper acetylacetonate in benzene
Heating;
参考文献
Polozov, Alexander M.; Mustaphin, Albert H.; Khotinen, Alexander V.
Phosphorus, Sulfur and Silicon and the Related Elements, 1992 , vol. 73, # 1-4 p. 153 - 160
反应条件
copper acetylacetonate in benzene
3 h; Heating;
参考文献
Polozov, A. M.; Mustafin, A. Kh.
J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 5.1 p. 1039 - 1042,850 - 852
反应条件
copper acetylacetonate in benzene
3 h; Heating;
参考文献
Polozov, A. M.; Mustafin, A. Kh.
J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 5.1 p. 1039 - 1042,850 - 852
