α-D(+)-五乙酰葡萄糖合成路线 （共 168 条）
反应条件
lipase from Pseudomonas fluorescens; phosphate buffer pH 7 in acetonitrile var. pH, var. lipases; Product distribution;
参考文献
Bastida, Agatha; Fernandez-Lafuente, Roberto; Fernandez-Lorente, Gloria; Guisan, Jose M.; Pagani, Giuseppe; Terreni, Marco
Bioorganic and Medicinal Chemistry Letters, 1999 , vol. 9, # 4 p. 633 - 636
反应条件
1: 78 percent / HF, pyridine / 4 h / Ambient temperature 2: 85 percent / NaOMe / methanol / 1 h / Ambient temperature View Scheme
参考文献
Horneman, Anne Marie; Lundt, Inge
Journal of Carbohydrate Chemistry, 1995 , vol. 14, # 1 p. 1 - 8
反应条件
pyridine; hydrogen fluoride 4 h; Ambient temperature;
参考文献
Horneman, Anne Marie; Lundt, Inge
Journal of Carbohydrate Chemistry, 1995 , vol. 14, # 1 p. 1 - 8
反应条件
in ethanol T=20°C; 24 h;
参考文献
Franceschin, Marco; Lombardo, Caterina Maria; Pascucci, Emanuela; D'Ambrosio, Danilo; Micheli, Emanuela; Bianco, Armandodoriano; Ortaggi, Giancarlo; Savino, Maria
Bioorganic and Medicinal Chemistry, 2008 , vol. 16, # 5 p. 2292 - 2304
反应条件
1: HBr / acetic acid / Ambient temperature 2: 43 percent / aq. NaOH / acetone / 7 h / Ambient temperature 3: 6mM methanolic MeONa / 5 h / Ambient temperature View Scheme
参考文献
Malet, Carles; Viladot, Josep Lluis; Ochoa, Ana; Gallego, Belen; Brosa, Carme; Planas, Antoni
Carbohydrate Research, 1995 , vol. 274, p. 285 - 302
反应条件
1.1: red phosphorus; Br2 / acetic anhydride / 25 °C 1.2: H2O / 13 h / 30 °C 2.1: 1.36 kg / NaOAc; CuSO4*5H2O; Zn / acetic acid; H2O / 50 °C View Scheme
参考文献
Apicore, LLC
Patent: US2013/5954 A1, 2013 ;
Location in patent: Page/Page column 15 ;
反应条件
1: hydrogen bromide; acetic acid / dichloromethane / Inert atmosphere 2: acetone / 70 - 80 °C / Inert atmosphere 3: Na2S2O5 / dichloromethane; water / 3 h / 60 °C / Inert atmosphere View Scheme
参考文献
Pearson, Samuel; Scarano, Wei; Stenzel, Martina H.
Chemical Communications, 2012 , vol. 48, # 39 p. 4695 - 4697
反应条件
1: 91.7 percent / red phosphorus, bromine, aq. HBr / acetic anhydride / 1 h / 40 - 50 °C 2: 95 percent / acetone / 0.5 h / Heating 3: 96 percent / K2CO3, NaHSO3 / acetone; H2O / Ambient temperature View Scheme
参考文献
Saito, Setsuo; Tsuchiya, Tomofusa
Chemical & Pharmaceutical Bulletin, 1985 , vol. 33, # 2 p. 503 - 508
反应条件
1: 91.7 percent / red phosphorus, bromine, aq. HBr / acetic anhydride / 1 h / 40 - 50 °C 2: 95 percent / acetone / 0.5 h / Heating 3: 96 percent / K2CO3, NaHSO3 / acetone; H2O / Ambient temperature 4: NaOH / methanol / Ambient temperature View Scheme
参考文献
Saito, Setsuo; Tsuchiya, Tomofusa
Chemical & Pharmaceutical Bulletin, 1985 , vol. 33, # 2 p. 503 - 508
反应条件
1: 91.7 percent / red phosphorus, bromine, aq. HBr / acetic anhydride / 1 h / 40 - 50 °C 2: 95 percent / acetone / 0.5 h / Heating 3: 94 percent / K2CO3, NaHSO3 / acetone; H2O / Ambient temperature 4: NaOH / methanol / Ambient temperature View Scheme
参考文献
Saito, Setsuo; Tsuchiya, Tomofusa
Chemical & Pharmaceutical Bulletin, 1985 , vol. 33, # 2 p. 503 - 508
