反应条件
1: 96 percent / AlH4 / diethyl ether / 2 h
2: 95 percent / PBr3 / diethyl ether / 2 h
3: 1.) CuI / 1.) THF, -40 deg C, 10 min, 2.) THF, -25 deg C, 2.5 h
4: 1.) Hg(OAc)2, 2.) NaBH4 / 1.) THF, H2O, 20 min, 2.) THF, H2O, 20 min
5: 1.) NaH / 1.) THF, RT, 45 min
6: tetrahydrofuran / 2 h / 65 °C
7: 1.) ethanethiol, NaH / 1.) DMF, RT, 1 h, 2.) DMF, 130 deg C, 6 h
8: 1.) NaH, 2.) NaI / 1.) HMPA, 30 min, 2.) HMPA, RT, 2 h
9: 80 percent / ethanethiol, NaH / dimethylformamide / 18 h / 120 °C
10: 92 percent / W-6 Raney nickel / ethanol / 3 h / Heating
View Scheme
参考文献
Cutler, Horace G.; Majetich, George; Tian, Xinrong; Spearing, Paul
Journal of Agricultural and Food Chemistry, 1997 , vol. 45, # 4 p. 1422 - 1429
