2,4,6-三硝基苯甲醚合成路线 （共 124 条）
参考文献
van Alphen
Recueil des Travaux Chimiques des Pays-Bas, 1930 , vol. 49, p. 153,159
参考文献
Jackson; Earle
American Chemical Journal, 1903 , vol. 29, p. 118
参考文献
van Alphen
Recueil des Travaux Chimiques des Pays-Bas, 1930 , vol. 49, p. 383,387
反应条件
1: 99 percent / CH3ONa, NH2OH*H2SO4 / methanol / 18 h / Ambient temperature
2: 100 percent / O3 / CH2Cl2 / 0.25 h / 0 - 5 °C
View Scheme
参考文献
Atkins, Ronald L.; Nielsen, Arnold T.; Bergens, Cynthia; Wilson, William S.
Journal of Organic Chemistry, 1984 , vol. 49, # 3 p. 503 - 507
参考文献
Cahours
Annales de Chimie (Cachan, France), 1849 , vol. <3> 27, p. 465
Justus Liebigs Annalen der Chemie, 1850 , vol. 74, p. 315
参考文献
Foster,R.; Mackie,R.K.
Journal of the Chemical Society, 1963 , p. 3796 - 3801
参考文献
Artamkina, G. A.; Egorov, M. P.; Beletskaya, I. P.; Reutov, O.A.
Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, # l p. 25 - 31
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 1 p. 29 - 36
反应条件
in tetrahydrofuran
formation of intermediate σ-complex, NMR spectrum of the σ-complex; Product distributionMechanism;
参考文献
Artamkina, G. A.; Egorov, M. P.; Beletskaya, I. P.; Reutov, O.A.
Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, # l p. 25 - 31
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 1 p. 29 - 36
反应条件
in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=-40°C; formation of intermediate σ-complex, NMR spectrum of the complex; Product distribution;
参考文献
Artamkina, G. A.; Egorov, M. P.; Beletskaya, I. P.; Reutov, O.A.
Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, # l p. 25 - 31
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 1 p. 29 - 36
反应条件
in tetrahydrofuran
T=-40°C; formation of intermediate σ-complex, NMR spectrum of σ-complex, UV spectrum of σ-complex; Product distribution;
参考文献
Artamkina, G. A.; Egorov, M. P.; Beletskaya, I. P.; Reutov, O.A.
Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, # l p. 25 - 31
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 1 p. 29 - 36
