2,2,2-三氟-1-(9-蒽基)乙醇合成路线 （共 9 条）
反应条件
1-tert-butyl-4,4,4-tris(dimethylamino)-2,2-bis[tris(dimethylamino)-phosphoranylidenamino]-2Λ54Λ5-catenadi(phosphazene) in tetrahydrofuran; hexane T=-30°C; 2 h; Schlenk techniqueInert atmosphere;
参考文献
Kawai, Hiroyuki; Yuan, Zhe; Tokunaga, Etsuko; Shibata, Norio
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 9 p. 1446 - 1450
反应条件
zinc in pyridine T=20°C; P=1500.1 - 3000.2 Torr; 4 h;
参考文献
Tordeux, Marc; Francese, Catherine; Wakselman, Claude
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 7 p. 1951 - 1957
反应条件
boron trifluoride diethyl etherate T=20°C; 3.5 h;
参考文献
Sanchez-Aris, Marta; Estivill, Carla; Virgili, Albert
Tetrahedron Asymmetry, 2003 , vol. 14, # 20 p. 3129 - 3135
反应条件
water; ammonium chloride in diethyl ether
参考文献
Journal of Organic Chemistry, , vol. 78, # 15 p. 7749 - 7753
参考文献
RUDJER BOSKOVIC INSTITUTE
Patent: WO2009/109792 A1, 2009 ;
Location in patent: Page/Page column 16 ;
反应条件
Birman's catalyst; sodium sulfate; N-ethyl-N,N-diisopropylamine in chloroform T=0°C; 1 h; Resolution of racemate; Kinetics; Reagent/catalyst; optical yield given as percent eeenantioselective reaction;
参考文献
Li, Ximin; Jiang, Hui; Uffman, Eric W.; Guo, Lei; Zhang, Yuhua; Yang, Xing; Birman, Vladimir B.
Journal of Organic Chemistry, 2012 , vol. 77, # 4 p. 1722 - 1737
参考文献
RUDJER BOSKOVIC INSTITUTE
Patent: WO2009/109792 A1, 2009 ;
Location in patent: Page/Page column 16 ;
反应条件
Birman's catalyst; sodium sulfate; N-ethyl-N,N-diisopropylamine in chloroform T=0°C; 1 h; Resolution of racemate; Kinetics; Reagent/catalyst; optical yield given as percent eeenantioselective reaction;
参考文献
Li, Ximin; Jiang, Hui; Uffman, Eric W.; Guo, Lei; Zhang, Yuhua; Yang, Xing; Birman, Vladimir B.
Journal of Organic Chemistry, 2012 , vol. 77, # 4 p. 1722 - 1737
反应条件
Mukayama reagent; 1,8-diazabicyclo[5.4.0]undec-7-ene in dichloromethane T=-78 - 20°C; 2 h;
参考文献
Matsuo, Jun-Ichi; Iida, Daisuke; Tatani, Kazuya; Mukaiyama, Teruaki
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 2 p. 223 - 234
