1,3-二甲基-2-碘苯合成路线 （共 73 条）
反应条件
1: With isopropylmagnesium chloride in tetrahydrofuran T=0°C; Inert atmosphere; 2: With methanol in tetrahydrofuran Kinetics; ConcentrationTime;
参考文献
Organic Letters, , vol. 14, # 10 p. 2602 - 2605
反应条件
1.1: 3-chloro-benzenecarboperoxoic acid; boron trifluoride diethyl etherate / dichloromethane / 0.5 h / 20 °C 1.2: 0.5 h / 320 °C 2.1: N,N-dimethyl-formamide / 24 h / 130 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 19, # 31 p. 10334 - 10342
反应条件
copper(l) iodide; thiourea; L-proline; sodium t-butanolate in dimethyl sulfoxide T=90°C; 24 h; Inert atmosphere;
参考文献
Qiao, Shu; Xie, Kun; Qi, Junsheng
Chinese Journal of Chemistry, 2010 , vol. 28, # 8 p. 1441 - 1443
反应条件
[PdCl2(1,3-bis(diphenylphosphino)propane)]; sodium carbonate in N,N-dimethyl-formamide; 1,3,5-trimethyl-benzene T=60°C; P=2250.23 Torr; 18 h; Sealed tube;
参考文献
Organic Process Research and Development, , vol. 11, # 1 p. 39 - 43
反应条件
palladium on activated charcoal; 1,8-diazabicyclo[5.4.0]undec-7-ene in acetonitrile T=80°C; 20 h; Autoclave;
参考文献
Chemical Communications, , vol. 50, # 18 p. 2330 - 2333
反应条件
potassium carbonate in water Suzuki-Miyaura reaction; Heating;
参考文献
Song, Hyon Min; Moosa, Basem A.; Khashab, Niveen M.
Journal of Materials Chemistry, 2012 , vol. 22, # 31 p. 15953 - 15959
反应条件
C18H33P*CuCl; sodium t-butanolate in toluene T=120°C; Suzuki-Miyaura Coupling; 15 h; Inert atmosphereGlovebox;
参考文献
Zhou, Yiqing; You, Wei; Smith, Kevin B.; Brown, M. Kevin
Angewandte Chemie - International Edition, 2014 , vol. 53, # 13 p. 3475 - 3479
Angew. Chem., 2014 , vol. 126, # 13 p. 3543 - 3547,5
反应条件
CyPF-tBu; palladium diacetate; sodium t-butanolate in ethylene glycol dimethyl ether T=110°C; 8 h; Inert atmosphere;
参考文献
Fernandez-Rodriguez, Manuel A.; Hartwig, John F.
Journal of Organic Chemistry, 2009 , vol. 74, # 4 p. 1664 - 1672
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate in 1-methyl-pyrrolidin-2-one T=100°C; P=3750.38 Torr; 24 h; Inert atmosphereAutoclave; Reagent/catalyst; chemoselective reaction;
参考文献
Barnard, Christopher F.J.
Organic Process Research and Development, 2008 , vol. 12, # 4 p. 566 - 574
反应条件
C44H34Br2P2Pd; potassium carbonate in 1-methyl-pyrrolidin-2-one T=100°C; P=3750.38 Torr; 24 h; Inert atmosphereAutoclave; Reagent/catalyst; chemoselective reaction;
参考文献
Organic Process Research and Development, , vol. 12, # 4 p. 566 - 574
