反应条件
1.1: 2,2,6,6-tetramethylpiperidinyl-lithium; N,N,N',N,-tetramethylethylenediamine; copper(l) chloride / tetrahydrofuran / 2 h / 20 °C / |Schlenk technique; |Inert atmosphere
1.2: 20 °C / |Schlenk technique; |Inert atmosphere
2.1: potassium carbonate; PCy3∙HBF4; palladium diacetate / N,N-dimethyl-formamide / 24 h / 130 °C / |Schlenk technique; |Inert atmosphere
View Scheme
参考文献
Marquise, Nada; Harford, Philip J.; Chevallier, Floris; Roisnel, Thierry; Dorcet, Vincent; Gagez, Anne-Laure; Sable, Sophie; Picot, Laurent; Thiery, Valerie; Wheatley, Andrew E.H.; Gros, Philippe C.; Mongin, Florence
Tetrahedron, 2013 , vol. 69, # 47 p. 10123 - 10133
