(5-氯-2-(甲氧基甲氧基)苯基)硼酸合成路线 (共 2 条)
反应条件
1: With N,N,N',N,-tetramethylethylenediamine; sec.-butyllithium in diethyl ether; hexane
T=-78°C; 1 h;
2: With boric acid trimethyl ester in diethyl ether; hexane
T=-78 - 20°C;
3: With ammonium chloride in diethyl ether; hexane
T=20°C; pH=6; Further stages.;
参考文献
Nerdinger; Kendall; Cai; Marchart; Riebel; Johnson; Yin; Henaff; Eltis; Snieckus
Journal of Organic Chemistry, 2007 , vol. 72, # 16 p. 5960 - 5967
反应条件
1: p-MOMOC6H4Cl With n-butyllithium in tetrahydrofuran; hexane
T=0°C; 2 h;
2: boric acid trimethyl ester in tetrahydrofuran; hexane
1 h;
3: With water; ammonium chloride in tetrahydrofuran; hexane
1 h;
参考文献
Oishi; Yamamoto
Bulletin of the Chemical Society of Japan, 2001 , vol. 74, # 8 p. 1445 - 1454