顺式,顺式-2,4-己二烯合成路线 （共 30 条）
反应条件
T=400°C; P=2 Torr; 2.77778E-06 h; Product distribution;
参考文献
Lei, Deqing; Gaspar, Peter P.
Journal of the Chemical Society, Chemical Communications, 1985 , # 17 p. 1149 - 1151
反应条件
1: aq. NaOH, <PhCH2NEt3>Cl 2: NaOMe / methanol 3: KOtBu 4: MeLi 5: 270 °C View Scheme
参考文献
Minter,D.E.; Fonken,G.J.
Tetrahedron Letters, 1977 , p. 4149 - 4152
反应条件
1: (Z)-MeCH=CHMgX With indium(III) chloride in tetrahydrofuran
T=20°C; 1 h;
2: 2-methyl-cyclohex-2-en-1-yl acetate With triphenylphosphine; tris-(dibenzylideneacetone)dipalladium(0) in tetrahydrofuran
参考文献
Baker, Lucas; Minehan, Thomas
Journal of Organic Chemistry, 2004 , vol. 69, # 11 p. 3957 - 3960
反应条件
bis(1,5-cyclooctadiene)nickel (0) in N,N-dimethyl-formamide
T=25°C; 14 h; Yield given. Yields of byproduct given;
参考文献
Semmelhack, M.F.; Helquist, Paul; Jones, L.D.; Keller, Leonard; Mendelson L.; et al.
Journal of the American Chemical Society, 1981 , vol. 103, # 21 p. 6460 - 6471
反应条件
in gas
P=0.1 - 0.2 Torr; Irradiationradio frequency plasma;
参考文献
Miller,L.L.; Mizobuchi,Y.
Journal of the American Chemical Society, 1978 , vol. 108, p. 5276
反应条件
(iPr4Anthraphos)Ir(C2H4)
T=180°C; 3.5 h; Inert atmosphereSealed vessel;
参考文献
THE UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL; BROOKHART, Maurice; FINDLATER, Michael; GUIRONNET, Damien; LYONS, Thomas Warren
Patent: WO2012/61272 A2, 2012 ;
Location in patent: Page/Page column 8-9 ;
反应条件
in gas
P=0.1 - 0.2 Torr; Irradiationradio frequency plasma;
参考文献
Miller,L.L.; Mizobuchi,Y.
Journal of the American Chemical Society, 1978 , vol. 108, p. 5276
反应条件
NiBr2(PPh3)2 in diethyl ether
1.) -78 deg C, 2.) 0 deg C, 50 min, 3.) 25 deg C, 4 h; Yield given. Yields of byproduct given;
参考文献
Semmelhack, M.F.; Helquist, Paul; Jones, L.D.; Keller, Leonard; Mendelson L.; et al.
Journal of the American Chemical Society, 1981 , vol. 103, # 21 p. 6460 - 6471
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; thiourea; potassium iodide; nickel dichloride; zinc
T=50°C; 0.5 h; Yield given;
参考文献
Takagi, Kentaro; Hayama, Naomi
Chemistry Letters, 1983 , p. 637 - 638
反应条件
in diethyl ether
decompn. at room temp.;;
参考文献
Whitesides,G.M. et al.
Journal of the American Chemical Society, 1971 , vol. 93, # 6 p. 1379 - 1389
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Whitesides, G. M.; Casey, C. P.
Journal of the American Chemical Society, 1966 , vol. 88, p. 4541 - 4543
Full Text Show Details
Gmelin Handbook: Ag: MVol.B5, 1.1.2, page 6 - 8
