4-(3,4-二羟基苯基)-2-丁酮合成路线 （共 6 条）
反应条件
boron tribromide in dichloromethane
T=-30°C;
参考文献
Pabst, Anni; Barron, Denis; Adda, Jacques; Schreier, Peter
Phytochemistry (Elsevier), 1990 , vol. 29, # 12 p. 3853 - 3858
反应条件
ammonium formate; acetone; palladium on activated charcoal in methanol
T=20°C; 1 h;
参考文献
Baranovsky, Alexander; Schmitt, Bettina; Fowler, Daniel J.; Schneider, Bernd
Synthetic Communications, 2003 , vol. 33, # 6 p. 1019 - 1045
反应条件
1: 43 percent / H2 / 10percent Pd/C / 3 h / Ambient temperature
2: BBr3 / CH2Cl2 / -30 °C
View Scheme
参考文献
Pabst, Anni; Barron, Denis; Adda, Jacques; Schreier, Peter
Phytochemistry (Elsevier), 1990 , vol. 29, # 12 p. 3853 - 3858
反应条件
1: 63 percent / aq. NaOH / 48 h / Ambient temperature
2: 43 percent / H2 / 10percent Pd/C / 3 h / Ambient temperature
3: BBr3 / CH2Cl2 / -30 °C
View Scheme
参考文献
Pabst, Anni; Barron, Denis; Adda, Jacques; Schreier, Peter
Phytochemistry (Elsevier), 1990 , vol. 29, # 12 p. 3853 - 3858
反应条件
1: 53 percent / piperidine; acetic acid; molecular sieves 4 Angstroem / acetonitrile / 4 h / Heating
2: 90 percent / ammonium formate; acetone / Pd/C / methanol / 1 h / 20 °C
View Scheme
参考文献
Baranovsky, Alexander; Schmitt, Bettina; Fowler, Daniel J.; Schneider, Bernd
Synthetic Communications, 2003 , vol. 33, # 6 p. 1019 - 1045
反应条件
sodium tetrahydroborate in methanol; diethyl ether
0.25 h; Ambient temperature; Yield given;
参考文献
Jetter, Reinhard; Klinger, Adelheid; Schaeffer, Stefanie
Phytochemistry, 2002 , vol. 61, # 5 p. 579 - 587
