N,N-二苯基-1-萘胺合成路线 （共 10 条）
反应条件
palladium diacetate; sodium t-butanolate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in neat (no solvent)
T=110°C; Buchwald-Hartwig Coupling; 12 h; Green chemistry;
参考文献
Topchiy, Maxim A.; Asachenko, Andrey F.; Nechaev, Mikhail S.
European Journal of Organic Chemistry, 2014 , vol. 2014, # 16 p. 3319 - 3322
反应条件
bis(1,5-cyclooctadiene)nickel (0); C{N(2,6-iPr2C6H3)CH}2 in tetrahydrofuran; 1,4-dioxane
T=150°C; Kumada Cross-Coupling; 24 h; Inert atmosphere;
参考文献
Tadaoka, Hiroshi; Yamakawa, Tetsu
Tetrahedron Letters, 2012 , vol. 53, # 41 p. 5531 - 5534
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate in toluene
8 h; Inert atmosphereReflux;
参考文献
Wu, Han-Yu; Wang, Kun-Li; Liaw, Der-Jang; Lee, Kueir-Rarn; Lai, Juin-Yih
Journal of Polymer Science, Part A: Polymer Chemistry, 2010 , vol. 48, # 7 p. 1469 - 1476
反应条件
cesium fluoride; bis(dibenzylideneacetone)-palladium(0); 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl
T=100°C; 3 h; Inert atmosphere;
参考文献
Shimizu, Kenta; Minami, Yasunori; Goto, Osamu; Ikehira, Hideyuki; Hiyama, Tamejiro
Chemistry Letters, 2014 , vol. 43, # 4 p. 438 - 440
反应条件
copper(l) iodide; sodium hydride in various solvent(s)
T=175°C; 24 h;
参考文献
Paine, Anthony James
Journal of the American Chemical Society, 1987 , vol. 109, # 5 p. 1496 - 1502
反应条件
cesium fluoride in acetonitrile
T=20°C; 72 h;
参考文献
Liu, Zhijian; Larock, Richard C.
Journal of Organic Chemistry, 2006 , vol. 71, # 8 p. 3198 - 3209
反应条件
1: diphenylamine With Ni(PCy3)2Cl2; isopropylmagnesium chloride; tri-cyclo-hexyl-phosphine in tetrahydrofuran; 1,4-dioxane
T=20°C; 0.0833333 h; Inert atmosphere;
2: alpha-chloronaphthalene in tetrahydrofuran; 1,4-dioxane
T=20 - 95°C; 12.16 h; Inert atmosphere;
参考文献
Li, Xin-Le; Wu, Wei; Fan, Xin-Heng; Yang, Lian-Ming
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 8 p. 1232 - 1236
反应条件
1: 1-(N-phenylamino)-naphthalene With Ni(PCy3)2Cl2; isopropylmagnesium chloride; tri-cyclo-hexyl-phosphine in tetrahydrofuran; 1,4-dioxane
T=20°C; 0.0833333 h; Inert atmosphere;
2: chlorobenzene in tetrahydrofuran; 1,4-dioxane
T=20 - 95°C; 12.16 h; Inert atmosphere;
参考文献
Li, Xin-Le; Wu, Wei; Fan, Xin-Heng; Yang, Lian-Ming
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 8 p. 1232 - 1236
反应条件
toluene-4-sulfonic acid in toluene
12 h; Heating;
参考文献
Haga, Kazuo; Iwaya, Katsumasa; Kaneko, Ryohei
Bulletin of the Chemical Society of Japan, 1986 , vol. 59, # 3 p. 803 - 808
反应条件
iron(III) oxide; potassium tert-butylate in dimethyl sulfoxide
T=130°C; 36 h; regioselective reaction;
参考文献
Alakonda, Laxhmaiah; Periasamy, Mariappan
Synthesis, 2012 , vol. 44, # 7 art. no. SS-2011-Z0977-OP, p. 1063 - 1068
