n-butyllithium
multistep reaction: intermediate substitution in the formation of a benzylic anion by an aromatic radical anion; other reagents (AH(-)Li(+), A(-*)Na(+), naphthalene(-*)Na(+)); Product distributionMechanism;
2-methylnitrobenzene; palladium on activated charcoal
T=230°C; 0.166667 h; var. hydrogen acceptors (also without acceptor); ΔH(excit.), ΔS(excit.); var. temp. and time; Rate constantKineticsThermodynamic data;
参考文献
Orchin
Journal of the American Chemical Society, 1944 , vol. 66, p. 535,537
vycor glass; zinc(II) chloride
T=80°C; P=0.0001 Torr; 1.5 h; also triphenylmethane; other temp. and time, other form of catalyst; Product distribution;
参考文献
Morita, Mikio; Hirosawa, Kunio; Sato, Toshio; Ouchi, Koji
Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 2 p. 540 - 544
