(S)-(-)-1-苯基-1-丙醇合成路线 （共 162 条）
反应条件
palladium diacetate; formic acid; tris-(o-tolyl)phosphine; TEA T=50°C;
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 52, # 1 p. 163 - 165
反应条件
benzoic acid anhydride; N-ethyl-N,N-diisopropylamine in dichloromethane T=20°C; 12 h; Title compound not separated from byproducts.;
参考文献
Tetrahedron Letters, , vol. 48, # 47 p. 8314 - 8317
反应条件
in toluene toluene-soln. of Zn-complex added benzaldehyde; cooled to 0°C; added Et2Zn; mixt. stirred at 0°C for 6 h; quenched (water); analyzed by HPLC;
参考文献
Journal of the American Chemical Society, , vol. 111, # 11 p. 4028 - 4036
反应条件
1: benzyl alcohol With C42H26N4O6Ru; dihydrogen peroxide in dichloromethane T=20°C; 2: diethylzinc With titanium (IV) isopropoxide in dichloromethane T=-10°C; 96 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Tetrahedron Letters, , vol. 51, # 17 p. 2345 - 2347
反应条件
Birman's catalyst; N-ethyl-N,N-diisopropylamine in dichloromethane T=20°C; 12 h; optical yield given as percent eeenantioselective reaction;
参考文献
Heterocycles, , vol. 77, # 2 p. 801 - 810
反应条件
1: With CF3O3S(1-)*C45H39N2OPRh(1+); benzo[1,3,2]dioxaborole in tetrahydrofuran T=20°C; Inert atmosphere; 2: With dihydrogen peroxide; sodium hydroxide in ethanol; water T=0 - 20°C; optical yield given as percent eeenantioselective reaction;
参考文献
Tetrahedron Asymmetry, , vol. 21, # 11-12 p. 1458 - 1473
反应条件
(S)-4-phenyl-1,4-diazalt;4.3.0gt;bicyclononane; diisobutylaluminium hydride; tin(ll) chloride in dichloromethane T=-100°C; 0.166667 h; Title compound not separated from byproducts;
参考文献
Gazzetta Chimica Italiana, , vol. 119, # 9 p. 511 - 512
反应条件
Paecilomyces sp biotransformation by diverse microorganisms, conversion percent, enantiomeric excess;
参考文献
Journal of Organic Chemistry, , vol. 63, # 22 p. 7598 - 7599
反应条件
tetra-n-butylammonium tetrafluoroborate; (1R,2S)-(-)-N,N-dimethylephedrinium tetrafluoroborate in water; N,N-dimethyl-formamide Electrolysis;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 75, # 3 p. 587 - 588
反应条件
1: triethylaluminum With titanium(IV) isopropylate; (S)-2-hydroxy-3-phenylpropionic acid in tetrahydrofuran; toluene T=18°C; 4 h; 2: benzaldehyde in tetrahydrofuran; toluene T=18°C; 4 h; Title compound not separated from byproducts;
参考文献
Tetrahedron Asymmetry, , vol. 16, # 4 p. 851 - 855
