(S)-(-)-1-苯基-1-丙醇合成路线 （共 162 条）
反应条件
(R)-(+)-N-methylbenzoguanidine; trimethylacetic anhydride in diethyl ether T=20°C; 12 h; Resolution of racemate; optical yield given as percent ee;
参考文献
Organic and Biomolecular Chemistry, , vol. 9, # 20 p. 7092 - 7096
反应条件
α-amino amid derived from L-phenylanaline (R'=Bn); nickel diacetate in methanol; toluene T=20°C; 24 h;
参考文献
Tetrahedron Letters, , vol. 44, # 36 p. 6891 - 6894
反应条件
(RP,S)-C16H15OC(Me)NCH(Me)Ph in hexane T=20°C; 12 h;
参考文献
Organic Letters, , vol. 6, # 13 p. 2113 - 2116
反应条件
[(C4Ph4COHOCC4Ph4)(μ-H)][(CO)4Ru2]; Novozym(R) 435; 2,4-dimethylpentan-3-one in toluene T=70°C; P=142.511 Torr; 40 h;
参考文献
Tetrahedron Asymmetry, , vol. 16, # 9 p. 1603 - 1610
反应条件
catalyst: (-)-3-exo-(dimethylamino)isoborneol in toluene toluene-soln. of catalyst added Me2Zn at 30°C; after 15 min added Et2Zn; cooled to 0°C; added benzaldehyde; mixt. stirred at 0°C for 6 h; quenched (water); analyzed by HPLC;
参考文献
Journal of the American Chemical Society, , vol. 111, # 11 p. 4028 - 4036
反应条件
SPB; water in tetrahydrofuran T=22°C;
参考文献
Angewandte Chemie, International Edition, , vol. 48, # 33 p. 6062 - 6064
Angewandte Chemie, , vol. 121, # 33 p. 6178 - 6180
反应条件
Birman's catalyst; nicotinic anhydride in dichloromethane T=0°C; 12 h; Resolution of racemate; optical yield given as percent eeenantioselective reaction;
参考文献
Heterocycles, , vol. 80, # 1 p. 169 - 175
反应条件
(-)-(R,R)-TADDOL in tetrahydrofuran T=-105°C; Title compound not separated from byproducts;
参考文献
Tetrahedron, , vol. 50, # 20 p. 6117 - 6128
反应条件
titanium(IV) isopropylate; (R)-2,2'-dihydroxy-1,1'-binaphthyl in tetrahydrofuran; toluene T=0°C; 5 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 119, # 17 p. 4080 - 4081
反应条件
sodium sulfate; N-ethyl-N,N-diisopropylamine; Birman's catalyst in chloroform T=0°C; 36 h; Title compound not separated from byproducts;
参考文献
Organic Letters, , vol. 8, # 7 p. 1351 - 1354
