2,2,7,7-四甲基-3,5-辛二炔合成路线 （共 34 条）
反应条件
in neat (no solvent) under Ar atm. excess Me2AlH and di(tert-butyl)butadiyne were stirred at 100°C for 1.5 h; react. mixt. was cooled to room temp., volatiles were removed in vacuo, residue was dissolved in n-pentane and cooled to -15°C;
参考文献
Uhl, Werner; Vinogradov, Andrej; Grimme, Stefan
Journal of the American Chemical Society, 2007 , vol. 129, # 36 p. 11259 - 11264
反应条件
in hexane T=20°C; Cycloaddition; 9 h; Photolysis;
参考文献
Ostendorf, Detlev; Kirmaier, Lars; Saak, Wolfgang; Marsmann, Heinrich; Weidenbruch, Manfred
European Journal of Inorganic Chemistry, 1999 , # 12 p. 2301 - 2307
反应条件
1: Li / tetrahydrofuran / 1) -10 deg C, 3 h, 2) 0 deg C, 1 h
View Scheme
参考文献
Neugebauer, Wolfgang; Geiger, Gottfried A. P.; Kos, Alexander J.; Stezowski, John J.; Schleyer, Paul von Rague
Chemische Berichte, 1985 , vol. 118, # 4 p. 1504 - 1516
反应条件
lithium in tetrahydrofuran
1) -10 deg C, 3 h, 2) 0 deg C, 1 h; Yield given;
参考文献
Neugebauer, Wolfgang; Geiger, Gottfried A. P.; Kos, Alexander J.; Stezowski, John J.; Schleyer, Paul von Rague
Chemische Berichte, 1985 , vol. 118, # 4 p. 1504 - 1516
