Mo(NMe2)4-SiO2 activated at 110 deg C in gas
T=110°C; P=10 - 20 Torr; other SiO2 supported catalyst derived from Mo2(NMe2)6, var. catalyst activation temperatures; specific activity in dimerization, homologation and metathesis, kinetic isotope effect; Product distributionMechanism;
参考文献
Zhuang, Quan; Tanaka, Katsumi; Ichikawa, Masaru
Journal of the Chemical Society, Chemical Communications, 1990 , # 21 p. 1477 - 1478
Weeks, Thomas J.; Ladd, Irwin R.; Bolton, Anthony P.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1980 , vol. 76, p. 84 - 91
Titanium(IV) oxide
Ambient temperatureIrradiationin the presence of O2; without photoirradiation; with heating from room temp. to 723 K; Product distributionMechanism;
参考文献
Muggli, Darrin S.; Larson, Sheldon A.; Falconer, John L.
Journal of Physical Chemistry, 1996 , vol. 100, # 39 p. 15886 - 15889