4 A molecular sieve; potassium acetate; tert-butylamine hydrochloride; palladium diacetate in N,N-dimethyl-formamide
T=80°C; Heck reaction; 18 h;
参考文献
Maeda, Kenji; Farrington, Edward J.; Galardon, Erwan; John, Benjamin D.; Brown, John M.
Advanced Synthesis and Catalysis, 2002 , vol. 344, # 1 p. 104 - 109
4 A molecular sieve; sodium acetate; trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) in N,N-dimethyl-formamide
T=80°C; Heck reaction; 18 h; Title compound not separated from byproducts.;
参考文献
Maeda, Kenji; Farrington, Edward J.; Galardon, Erwan; John, Benjamin D.; Brown, John M.
Advanced Synthesis and Catalysis, 2002 , vol. 344, # 1 p. 104 - 109
1: 56 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene / toluene / 2 h / 100 °C
2: NaOAc; molecular sieves 4 Angstroem / Herrmann's catalyst / dimethylformamide / 18 h / 80 °C
View Scheme
参考文献
Maeda, Kenji; Farrington, Edward J.; Galardon, Erwan; John, Benjamin D.; Brown, John M.
Advanced Synthesis and Catalysis, 2002 , vol. 344, # 1 p. 104 - 109
